Determination of Thermodynamic Parameters for Adduct Reaction of 1,3-Diphenyl-l,3-Propanedione Copper CuC30H22O4 withFuran and Thiophen by GL-Chromatographic Method

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (10): 1044.

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Determination of Thermodynamic Parameters for Adduct Reaction of 1,3-Diphenyl-l,3-Propanedione Copper CuC₃₀H₂₂O₄ withFuran and Thiophen by GL-Chromatographic Method

Zhou Jingyu, Guo Boshu, Yao Yuangen, You Xiaozeng

Coordinatum Chemistry Institute, Nanjing University, Nanjing

Received:1988-03-01 Online:1989-10-24 Published:1989-10-24

Abstract

Abstract: Using the GLCmethod, soluble equilibrium constant K_R⁰ of Lewis bases furan C₄H₄Oand thiophen C₄H₄Sin the dibenzyl diphenyl solvent, and the apparent equilibrium constant K_Rfor the interaction between the two Lewis bases and the Lewis acid transition metal complex 1,3-diphenyl-1,3-propanedione copper at various temperatures are determined.

Key words: Adduct reaction, Equilibrium constant, Copper complex, 1, 3-diphenyl^-1, 3-propanedione

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Zhou Jingyu, Guo Boshu, Yao Yuangen, You Xiaozeng . Determination of Thermodynamic Parameters for Adduct Reaction of 1,3-Diphenyl-l,3-Propanedione Copper CuC₃₀H₂₂O₄ withFuran and Thiophen by GL-Chromatographic Method[J]. Chem. J. Chinese Universities, 1989, 10(10): 1044.

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Determination of Thermodynamic Parameters for Adduct Reaction of 1,3-Diphenyl-l,3-Propanedione Copper CuC₃₀H₂₂O₄ withFuran and Thiophen by GL-Chromatographic Method

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