Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (9): 1875.doi: 10.7503/cjcu20180467
• Articles:Inorganic Chemistry • Previous Articles Next Articles
FENG Wei1, WANG Bowei2, ZHENG Yan1, JIANG Yang1,*(
)
Received:2018-06-29
Online:2018-09-07
Published:2018-08-03
Contact:
JIANG Yang
E-mail:jiangyang@jlu.edu.cn
Supported by:CLC Number:
TrendMD:
FENG Wei,WANG Bowei,ZHENG Yan,JIANG Yang. Preparation and Surface-enhanced Raman Scattering(SERS) of Single Au Nanodot†[J]. Chem. J. Chinese Universities, 2018, 39(9): 1875.
Fig.1 Preparation process of metal nanodot arraysh Represents the height of the metal nanodot, d is the diameter of the nanodot on top view, while D descripts the diameter of the polystyrene sphere.
Fig.2 AFM images of the gold nanodot with height phase(A, C) and amplitude phase(B, D)
Fig.3 SEM image of single Au nanodot on the PS sphere array(inset) and SERS spectrum of 0.5 mol/L pyridine on a single Au nanodot
Fig.4 SERS spectrum of benzenethiol monolayer on a single Au nanodot
Fig.5 SERS spectrum of R6G monolayer on a single Au nanopdot
Fig.6 Raman spectrum of pyridine
Fig.7 Raman spectrum of thiolbenzene
Fig.8 Raman spectrum of R6G monolayer
| λex/nm | G(SERS/Pyridine) | G(SERS/R6G) | |||||||
|---|---|---|---|---|---|---|---|---|---|
| 1010 cm-1 | 1034 cm-1 | 417 cm-1 | 998 cm-1 | 1019 cm-1 | 1569 cm-1 | 609 cm-1 | 1370 cm-1 | 1648 cm-1 | |
| 632.8 | 4.87×105 | 1.57×105 | 3.94×105 | 1.77×105 | 3.7×105 | 6.42×105 | 4.57×104 | 3.98×104 | 8.38×103 |
Table 1 Enhancement factors of Au naonparticle
| λex/nm | G(SERS/Pyridine) | G(SERS/R6G) | |||||||
|---|---|---|---|---|---|---|---|---|---|
| 1010 cm-1 | 1034 cm-1 | 417 cm-1 | 998 cm-1 | 1019 cm-1 | 1569 cm-1 | 609 cm-1 | 1370 cm-1 | 1648 cm-1 | |
| 632.8 | 4.87×105 | 1.57×105 | 3.94×105 | 1.77×105 | 3.7×105 | 6.42×105 | 4.57×104 | 3.98×104 | 8.38×103 |
Fig.9 Raman spectrum of polystyrene sphere(with a diameter of 2.55 mm) etched for 50 min, excitated at 632.8 nm
Fig.10 SERS spectrum of polystyrene sphere on a gold nanodot
| [1] | Fleischmann M., Hendra P. J., McQuillan A. J., Chem. Phys. Lett., 1974, 26, 163—166 |
| [2] | Jeanmaire D. L., van Duyne R. P., J. Electroanal. Chem. Interf. Electrochem., 1977, 84, 1—20 |
| [3] | Sebastian S., Angew. Chem. Int. Ed., 2014, 53, 4756—4795 |
| [4] | Cialla D., Marz A., Bohme R., Anal. Bioanal. Chem., 2012, 403(1), 27—54 |
| [5] | Han X. X., Zhao B., Ozaki Y., Anal. Bioanal. Chem., 2009, 394(8), 1719—1727 |
| [6] | Yui H., Anal. Bioanal. Chem., 2010, 397(3), 1181—1190 |
| [7] | Eduardo G. R., Ramon A. A. P., Luca G., Chem. Soc. Rev., 2018, 47, 4909—4923 |
| [8] | Halvorson R. A., Vikesland P. J., Environ. Sci. Technol., 2010, 44(20), 7749—7755 |
| [9] | Sebastien B., Sophie L., Chem. Phys. Chem., 2018, 19, 8—18 |
| [10] | Chou S. Y., Yu C. C., Yen Y. T., Lin K. T., Chen H. L., Su W. F., Anal. Chem., 2015, 87, 6017—6024 |
| [11] | Wu H. Y., Huang W. L., Michael H. H., Cryst. Growth Des., 2007, 7(4), 831—835 |
| [12] | Sun Y. G., Xia Y. N., Science, 2002, 298, 2176—2179 |
| [13] | Kim D. Y., Yu T., Cho E. C., Angew. Chem. Int. Ed., 2011, 50(28), 6328—6331 |
| [14] | Chen C. L., Furusho H., Mori H., Nanotechnology, 2009, 20(40), 5605—5608 |
| [15] | Ashkin A., Dziedzic J. M., Bjorkholm J. E., Chu S., Opt. Lett., 1986, 11, 288—290 |
| [16] | Svoboda K., Block M., Opt. Lett., 1994, 19, 930—932 |
| [17] | Prikulis J., Svedberg F., Kall M., Enger J., Ramser K., Goksor M., Hanstorp D., Nano Lett., 2004, 4, 115—118 |
| [18] | Svedberg F., Kall M., Svedberg F., Kall M., Faraday Discuss., 2006, 132, 35—44 |
| [19] | Zhang G., Wang D.Y., Chem. Asian J., 2009, 4(2), 236—245 |
| [20] | Ai B., Mohwald H., Wang D. Y., Zhang G., Adv. Mater. Interfaces, 2017, 4, 1600271 |
| [21] | Zhang G., Wang D. Y., Mohwald H., Nano Lett., 2005, 5(1), 143—146 |
| [22] | Zhang G., Wang D. Y., Mohwald H., Angew. Chem. Int. Ed., 2005, 44(47), 7767—7770 |
| [23] | Xu H., Aizpurua J., Kall M., Apell P., Phys. Rev. E, 2000, 62, 4318—4324 |
| [24] | Liao P. F., Wokaun A., J. Chem. Phys., 1982, 76, 751—752 |
| [25] | Boyd G. T., Rasing T., Leite J. R. R., Shen Y. R., Phys. Rev. B, 1984, 30, 519—522 |
| [26] | Chen C. Y., Burstein E., Phys. Rev. Lett., 1980, 45, 1287—1291 |
| [27] | Inoue M., Ohtaka K., J. Phys. Soc. Jpn., 1983, 52, 3853—3864 |
| [28] | Dollish F. R., Fateley W. G., Bentley F. F., Characteristic Raman Frequencies of Organic Compounds, John Willey & Sons, New York, 1973 |
| [29] | Lee I., Han S. W., Kim K., J. Raman Spectrosc., 2001, 32, 947—952 |
| [30] | Carron K. T., Hurley L. G., J. Phys. Chem. B, 2005, 95, 9979—9984 |
| [31] | Nie S. M., Lipscomb L. A., Yu N. T., Appl. Spectrosc. Rev., 1991, 26(3), 203—276 |
| [32] | Majoube M., Henry M., Spectrochim. Acta, 1991, 47A, 1459—1466 |
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