Farbrication and Characterization of Flexible, Transparent and Self-standing Sb Doped SnO2 Electrospun Nanofiber Films†

doi:10.7503/cjcu20140667

Abstract

Abstract:

Flexible, transparent and self-standing Sb doped SnO₂(ATO) nanofiber films were successfully fabricated by means of a low-cost and scalable electrospinning process, with tin tetrachloride and antimony trichloride as precursors. The as-prepared ATO nanofiber films are typical interconnected nanofiber networks and show a single SnO₂ rutile crystal structures. With increasing the calcination temperature from 520 ℃ to 700 ℃, the average diameter of ATO nanofibers decrease from 200 nm to 150 nm, but accompanied by an increase in the average diameter of ATO nanoparticles. Meanwhile, the transmittance of the ATO nanofiber film increases from 72% to 80%, while their resistance decreases from 5.23 Ω·cm to 2.20 Ω·cm. Importantly, after 500 cycles of bending, the self-standing ATO nanofibers show no obvious electrical degradation. The ATO nanofiber films show promise for application in many fields, such as flexible liquid crystal displays, solar cells and flexible and transparent functional electronics.

Key words: Electrospinning, Sb Doped SnO2(ATO) nanofiber, Self-standing, Flexible conducting film

CLC Number:

O614.43

TrendMD:

KONG Zhuang, LI Yong, LU Xianyong, ZHU Ying, JIANG Lei. Farbrication and Characterization of Flexible, Transparent and Self-standing Sb Doped SnO₂ Electrospun Nanofiber Films^†[J]. Chem. J. Chinese Universities, 2015, 36(1): 55.

Figures/Tables 5

Fig.1 FE-SEM images(A,B) and TG-DSC curves(C) of electrospun precursor nanofibers

Fig.2 XRD patterns of ATO nanofiber films calcined at different temperatures(A) and EDS spectrum(B) and elemental mapping of Sn(C) and Sb(D) of ATO nanofiber calcined at 700 ℃

Fig.3 FE-SEM images of electrospun ATO nanofiber films calcined at 520 ℃(A1, A2), 600 ℃(B1, B2) and 700 ℃(C1, C2)

Fig.4 Digital photo of the folded ATO nanofiber films calcined at 700 ℃ for 3 h(A) and sheet resistance of the ATO nanofiber films after different times of bending(B) Inset of (B): Digital photo of the folded ATO nanofiber films(up) and digital photo of conducting ATO nanofiber electrode after 500 times of folding(down).

Fig.5 Reflection(A) and transmittance(B) spectra in the visible region of ATO nanofiber films calcined at 520 ℃(a), 600 ℃(b) and 700 ℃(c), respectively

References 22

[1]	Kenji N., Hiromichi O., Akihiro T., Toshio K., Masahiro H., Hideo H., Nature , 2004, 432, 488—492
[2]	Rainer O., Roman Z., Melanie R., Derck S., Bernd M. S., Chem. Commun., 2011, 47, 12119—12121
[3]	Sung U. L., Boo J. H., Hong B. Y., Jpn. J. Appl. Phys., 2011, 50, 01AB10
[4]	Liu Y. D., Li Q., Shao H. L., Vacuum , 2009, 83, 1435—1437
[5]	Sun B., Long Y. Z., Chen Z. J., Liu S. L., Zhang H. D., Zhang J. C., Han W. P., J. Mater. Chem. C, 2014, 2, 1209—1219
[6]	Wu H., Kong D., Ruan Z. C., Hsu P. C., Wang S., Yu Z., Carney T. J., Hu L., Fan S., Cui Y., Nat. Nanotechnol., 2013, 8, 421—425
[7]	Wu H., Hu L., Rowell M. W., Kong D., Cha J. J., McDonough J. R., Zhu J., Yang Y., McGehee M. D., Cui Y., Nano Lett., 2010, 10, 4242—4248
[8]	Hsu P. C., Wu H., Carney T. J., McDowell M. T., Yang Y., Garnett E. C., Li M., Hu L., Cui Y., ACS Nano., 2012, 6, 5150—5156
[9]	Li H., Pan W., Zhang W., Huang S., Wu H., Adv. Funct. Mater., 2013, 23, 209—214
[10]	Pan C., Dong L., Ma L., Yang G. J., Chem. J. Chinese Universities, 2013, 34(11), 2623—2628
	(潘超, 董丽, 马玲, 杨桂娟, 高等学校化学学报, 2013, 34(11), 2623—2628)
[11]	Fuh Y. K., Lien L. C., Nanotechnology , 2013, 24, 055301
[12]	Soltanian S., Rahmanian R., Gholamkhass B., Kiasari N. M., Ko F., Servati P., Adv. Energy Mater., 2013, 3, 1332—1337
[13]	Kim T. A., Lee S. S., Kim H., Park M., RSC Adv., 2012, 2, 10717—10742
[14]	Zhang Q., Xia K., Liu L., Liu Y. C., Zhang C., Liu X., Xu Y., Cheng S. J., Chen J. D., Chem. J. Chinese Universities, 2013, 34(11), 2667—2673
	(张谦, 夏柯, 刘丽, 刘又畅, 张翠, 刘璇, 徐缓, 陈世金, 陈际达, 高等学校化学学报,, 2013, 34(11), 2667—2673)
[15]	Wu H., Hu L. B., Carney T., Ruan Z. C., Kong D. S., Yu Z. F., Yao Y, Cha J. J., Zhu J., Fan S. H., Cui Y., J. Am. Chem. Soc., 2011, 133, 27—29
[16]	Muhammad M. M., Ferry I., Ki M. Y., Kikuo O., Mikrajuddin A., Nanotechnology , 2008, 19, 375601
[17]	Wang W. N., Widiyastuti W., Ogi T., Lenggoro I. W., Okuyama K., Chem. Mater., 2009, 19, 1723—1730
[18]	Li C. J., Zhai G. J., Fu Z. Y., Wang P. J., Chang M., Li X. N., Chinese J. Inorg. Chem., 2006, 22(11), 2061—2064
	(李从举, 翟国钧, 付中玉, 王佩杰, 常敏, 李小宁. 无机化学学报, 2006, 22(11), 2061—2064)
[19]	Li S.L., Zhu P.L., Zhao T., Sun R., J. Sol-Gel. Sci. Technol., 2014, 70, 366—370
[20]	Yang C. H., Lee S. C., Chen S. C., Lin T. C., Mater. Sci. Eng. B, 2006, 129, 154—160
[21]	Huang Y. L., Baji A., Tien H. W., Yang Y. K., Yang S. Y., Wu S. Y., Ma C. C. M., Liu H. Y., Mai Y. W., Wang N. H., Carbon , 2012, 50, 3473—3481
[22]	Yang S.Y., Tang X. M., Ge J. L., Yang S., Mohamed E. N., Salem S., Deyab A., Yuan J. Y., Ding B., Nanoscale , 2014, 6, 1602—1605

Farbrication and Characterization of Flexible, Transparent and Self-standing Sb Doped SnO₂ Electrospun Nanofiber Films^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 22

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WU Yu, LI Xuan, YANG Hengpan, HE Chuanxin. Construction of Cobalt Single Atoms via Double-confinement Strategy for High-performance Electrocatalytic Reduction of Carbon Dioxide [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220343.
[2]	HE Nan, LIU Wei, YANG Xia, WANG Xianze, CUI Xiaochun, WU Jinghui, GENG Zhi. Preparation and Performance of Self-standing NH₂-MIL-125/polyoxadiazole Composite Forward Osmosis Membranes ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1370.
[3]	WANG Xia, LIU Yanji, JIA Yongfeng, JI Lei, HU Quanli, DUAN Limei, LIU Jinghai. Preparative Chemistry of N-containing Porous Carbon Nanofibers for Capacity Improvement in Lithium-sulfur Battery ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 829.
[4]	QIN Chunping, WANG Xianliu, TANG Han, YI Bingcheng, LIU Chang, ZHANG Yanzhong. Osteogenesis-promoting Effects of the Electrospun Nanofibers Containing Decellularized Bone Matrix ^† [J]. Chem. J. Chinese Universities, 2020, 41(4): 780.
[5]	WANG Yongpeng,XU Zibo,LIU Mengzhu,ZHANG Haibo,JIANG Zhenhua. Non-enzymatic Glucose Sensor Based on the Electrospun Porous Foamy Copper Oxides Micro-nanofibers^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1310.
[6]	CAI Jiao,YU Qiongwei,HE Xiaomei,XU Jing,DING Qiong,FENG Yuqi. Preparation of SiW₁₁ Incorporated SiO₂ Nanofibers(SiW₁₁/SiO₂) and Its Application in the Analysis of Polyamines in Arabidopsis^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 901.
[7]	ZHAO Yuxuan,CHEN Yanjun,PAN Guxin,WANG Chang,PENG Zhenbo,SUN Zongxu,LIANG Yongri,SHI Qisong. Preparation and Performance of Novel Tb-PEG+Eu-PEG/PANI/PAN Luminescent-electrical-phase Change Composite Fibers by Electrospinning^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 824.
[8]	GAO Ningxiao,XU Yulong,LIU Yong. Preparation of Carbon Dots from Soy Milk Powder and Fluorescent Nanofibers Containing Carbon Dots^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 555.
[9]	ZHANG Xinmu,CUI Xiangxu,YAOMA Kangyue,LI Tingting,ZHANG Zhiming. Electrospinning Preparation and Photocatalytic Activity of H₄SiW₁₂O₄₀/Ethylene Vinyl Alcohol Copolymer Nanofibrous Membrane^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 372.
[10]	XU Dan,DING Yadan,WANG Xue,CONG Tie,LIU Junping,HONG Xia,PAN Ying. Microdroplet Detection of Protein Based on Superhydrophobic Polystyrene Film^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1913.
[11]	NIE Guangdi, ZHU Yun, TIAN Di, WANG Ce. Research Progress in the Electrospun Nanofiber-based Supercapacitor Electrode Materials^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1349.
[12]	ZHOU Ying, WANG Xianliu, YI Bingcheng, YU Zhepao, YANG Shangying, SHEN Yanbing, ZHANG Yanzhong. Engineering Shape Memory Enabled Composite Nanofibers for Bone Tissue Engineering^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1554.
[13]	HAN Zhiying, LI Youji, LIN Xiao, WANG Ziyu, LI Ziqin, WANG Hao. Preparation and Photoelectrocatalytic Performance of Fe₂O₃/ZnO Composite Electrode Loading on Conductive Glass^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 771.
[14]	REN Jing, WANG Shugang, LI Yanchun, YANG Qingbiao, SONG Yan, LI Yaoxian. Preparation of AOPAN@PAN Coaxial Nanofiber Membrane and It’s Adsorption Property^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 825.
[15]	LU Guanxiu, LIU Qingwen, KONG Xiangyi, CONG Lele, SONG Yan, ZHAO Qing, YANG Qingbiao, LI Yaoxian. Preparation of PVA/GA/β-CD Nanofibers and Its Adsorption of Dyestuff [J]. Chem. J. Chinese Universities, 2017, 38(8): 1465.