Synthesis and Properties of a Novel Organic Non-linear Optical Chromophore Containing Bifuran Conjugating Bridge

doi:10.7503/cjcu20121023

Chem. J. Chinese Universities ›› 2013, Vol. 34 ›› Issue (6): 1403.doi: 10.7503/cjcu20121023

• Organic Chemistry • Previous Articles Next Articles

Synthesis and Properties of a Novel Organic Non-linear Optical Chromophore Containing Bifuran Conjugating Bridge

REN Li-Ke¹, TANG Xian-Zhong¹, TANG Xiang¹, WANG Yang¹, YOU Ying-Cai¹, JIA Kun-Peng²

1. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China;
2. The 69316 Unit of People’s Liberation Army, Beijing 100036, China

Received:2012-11-12 Online:2013-06-10 Published:2013-05-10

Abstract

Abstract:

It has been demonstrated that organic second-order nonlinear chromophore, with hetero-aromatic ring as the conjugating bridge, has large hyperpolarizability. In this work, with the aim of studying the hyperpolarizability influenced by the length of conjugating bridge, a novel organic non-linear optics(NLO) chromophore MF₃C containing bifuran conjugating bridge, tricyanofuran as electron acceptor and dimethylamine as donor was synthesized through Wittig reactions and Vilsmeier reactions. The new chromophore was characte-rized by FTIR, ¹H NMR and elemental analysis. Thermogravimetric analysis(TGA) test revealed that the decomposition temperature(T_d) of the molecular was up to 228℃. Solvatochloroform method was used to calculate the hyperpolarizability(μ_gβ). We got the μ_gβ value of MF₃C led to 5.9×10^-44 esu at 1064 nm. With good thermal stability and large hyperpolarizability simultaneously, the chromophore shows great potential applications in electro-optic devices.

Key words: Organic non-linear optics, Bifuran conjugating bridge, Solvatochloroform

CLC Number:

O621

TrendMD:

REN Li-Ke, TANG Xian-Zhong, TANG Xiang, WANG Yang, YOU Ying-Cai, JIA Kun-Peng. Synthesis and Properties of a Novel Organic Non-linear Optical Chromophore Containing Bifuran Conjugating Bridge[J]. Chem. J. Chinese Universities, 2013, 34(6): 1403.

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Synthesis and Properties of a Novel Organic Non-linear Optical Chromophore Containing Bifuran Conjugating Bridge

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