高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (7): 1016.

• 研究快报 • 上一篇    下一篇

强绿荧光铽-异丁酰基吡唑啉酮配合物的合成、荧光性能及LB膜

李琴, 周德建, 姚光庆, 黄春辉, Umetani Shigeo, Matsui Masakazu   

  1. 1. 北京大学稀土材料化学及应用国家重点实验室, 北京 100871;
    2. 日本京都大学化学研究所
  • 收稿日期:1996-01-04 出版日期:1996-07-24 发布日期:1996-07-24
  • 通讯作者: 黄春辉
  • 作者简介:李琴,女,32岁,讲师,荆州师范专科学校化学系访问学者.
  • 基金资助:

    国家攀登计划;国家重点实验室资助

Synthesis,Fluorescence Charactcteristics and Langmuir-blodgett Film of a Green Strongly Fluorescent Terbium isobutyryl Pyrazolonee Complex

LI Qin, ZHOU De-Jian, YAO Guang-Qing, HUANG Chun-Hui, Umetani Shigeo, Matsui Masakazu   

  1. 1. State Key Laboratory fo Rare Earth Material Chemistry and Applications, Peking University, Beijing 100871;
    2. Institute of Chemical Research, Kyoto University, Uji, Kyoto 611, Japan
  • Received:1996-01-04 Online:1996-07-24 Published:1996-07-24

PDF (PC)

被引次数

2

关键词: 铽, 1-苯基-3-甲基-4-异丁酰基吡唑啉酮-5, 配合物, 荧光, LB膜

Abstract: Agreen strongly luminescent amphiphilic lanthanide complex:N-hexadecyl pyridinium tetrakis(1-phenyl-3-methyl-4-isobutyryl-pyrazolone-5)terbium was prepared and identified by elementary analysis.The Langmuir film on the air/water interface and the transfer of the Langmuir film to form LBfilms by conventional vertical dipping method were investigated.The fluorescence spectra and fluorescence lifetime of the complex at solid state,in CHCl3 solution and on the ordered LBfilm were studied.The results show that the title complex exhibits a good performance in both fluorescence and film formation and transformation,This provides valuable fundamental data for its further application in microcavity laseroscillators.

Key words: Terbium, 1-phenyl-3-methyl-4-isobutyryl-5-pyrazolone, Complex, Fluores-cence, LB film

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