高等学校化学学报 ›› 2023, Vol. 44 ›› Issue (2): 20220474.doi: 10.7503/cjcu20220474
收稿日期:
2022-07-11
出版日期:
2023-02-10
发布日期:
2022-08-30
通讯作者:
李云峰
E-mail:yflichem@jlu.edu.cn
基金资助:
DUAN Yixiong, YANG Bai, LI Yunfeng()
Received:
2022-07-11
Online:
2023-02-10
Published:
2022-08-30
Contact:
LI Yunfeng
E-mail:yflichem@jlu.edu.cn
Supported by:
摘要:
作为最有前途的生物衍生材料之一, 纤维素纳米晶体(CNCs)具有来源广泛、 生物相容性好和可形成光子结构等优点, 在能源、 生物医学和光子材料领域具有重要的应用价值. 本文总结了CNCs的制备、 CNCs形成的胆甾型胶体液晶及CNCs衍生的光子材料的研究进展, 重点评述了CNCs在液滴和毛细管中的自组装和基于CNCs空间受限组装的功能材料研究进展, 并讨论了空间受限CNCs自组装研究面临的挑战和未来的发展方向.
中图分类号:
TrendMD:
段一雄, 杨柏, 李云峰. 纤维素纳米晶的空间受限自组装: 从胶体液晶到功能材料. 高等学校化学学报, 2023, 44(2): 20220474.
DUAN Yixiong, YANG Bai, LI Yunfeng. Self-assembly of Cellulose Nanocrystals in Spatial Confinement: from Colloidal Liquid Crystals to Functional Materials. Chem. J. Chinese Universities, 2023, 44(2): 20220474.
Fig.1 Representative transmission electron micrographs of CNCs(A)[36] and representative atomic force microscope images of CNCs(B)[37](A) Copyright 2000, American Chemical Society; (B) Copyright 2021, Springer Nature.
Fig.2 Cholesteric liquid crystals of CNCs(A) The photographs illustrating the phase separation of the CNC suspensions into a top isotropic phase and a bottom cholesteric LC phase, the CNC concentrations increased from left to right, the pictures were taken under crossed polarizers; (B) the ratio of anisotropic phases as a function of the CNC concentrations; (C) polarized optical microscopy(POM) image of cholesteric LC of CNCs[52]; (D) bright-field(BF) images of the phase separation of mixed suspensions of CNCs and gold nanoparticles of different sizes[54].
Fig.3 Photonic materials derived from cholesteric LCs of CNCs(A) Photographs of the photonic elastomer based on the composites of CNCs with the elongation of 0, 65%, 250%, and 300%(left to right), respectively; the scale bar is 1 cm; (B) normalized reflectance spectra of photonic elastomers with different elongation[72]; (C) photographs of mesoporous photonic films derived from CNCs immersed in the mixture of ethanol and water with different ratios[70]; (D) actuation behaviors of the bilayer mesoporous photonic films derived from CNCs(top panel) and the photographs of the selectively deformed “fingers” on the hand-shaped mesoporous photonic film(bottom panel)[73].(A, B) Copyright 2019, Wiley-VCH; (C) Copyright 2014, Wiley-VCH; (D) Copyright 2014, Wiley-VCH.
Fig.4 Confined self⁃assembly of CNCs in the capillary(A) POM images at low (left) and high (right) magnifications of cholesteric CNC suspension confined in a 100 μm capillary, the scale bars are 100 μm; (B) schematic illustration of cholesteric LCs of CNCs in the capillary[75]; (C) photographs of continuous generation of liquid metacrystal fibers; (D) schematic illustration of the liquid crystal self-assembly of the CNCs in a cylindrical hydrogel tube during fiber production; (E) POM image of the radial section of liquid metacrystal fibers; (F) POM image of the axial direction of the liquid metacrystal fibers. Scale bars are 500 μm in (E) and (F)[34].
Fig.5 Confined self⁃assembly of CNCs in the droplets[31](A) Optical microscopy image of a microfluidic generation of droplets of cholesteric CNCs, the scale bar is 1 cm. POM image(B) and BF optical microscopy image(C) of cholesteric CNC droplets, the scale bars are 500 μm in (B) and 50 μm in (C). (D—F) POM images of the cholesteric CNC droplets of different confinement dimensions, the scale bars are 50 μm; (G—I) schematic illustration of cholesteric CNC packing in the droplets with different dimensions shown in (D), (E) and (F), respectively. White arrows in (C) and (D) show the defect of the radial disclination line, red arrow in (D) shows an edge dislocation running parallel to the cholesteric layers.
Fig.6 Confined coassembly of CNCs and nanoparticles in the droplet(A) BF optical microscopy images of droplets through the co-assembly of cholesteric CNCs and fluorescein isothiocyanate dye⁃ labelled 184 nm latex nanoparticles, the scale bar is 100 μm[31]; BF optical microscopy image(B), POM image(C) and fluorescent microscope image(D) of cholesteric CNC droplets loaded with fluorescein isothiocyanate dye-labelled 184 nm latex nanoparticles, the scale bars are 50 μm; (E, F) fluorescent microscope images of the arrays of beads, the CNC suspensions were treated by ultrasonication at the energy of 340 J/g(E) and 1364 J/g(F) CNCs, the scale bars are 5 μm; (G) variation in the periodicity of the bead array as a function of the half pitch of the cholesteric CNCs[32].(A) Copyright 2016, Springer Nature; (B—G) Copyright 2017, the National Academy of Sciences of the USA.
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