高等学校化学学报 ›› 2012, Vol. 33 ›› Issue (08): 1809.doi: 10.3969/j.issn.0251-0790.2012.08.032

• 物理化学 • 上一篇    下一篇

高透光性有序银网阵列的制备

贾若琨1, 林松竹1, 何爱民1, 赵晴潇1, 白玉白2   

  1. 1. 东北电力大学化学工程学院, 吉林 132012;
    2. 吉林大学化学学院, 长春 130012
  • 收稿日期:2011-10-08 出版日期:2012-08-10 发布日期:2012-08-10
  • 通讯作者: 贾若琨, 男, 博士, 副教授, 主要从事材料物理化学研究. E-mail: jiaruokun@mail.nedu.edu.cn E-mail:jiaruokun@mail.nedu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 51003010); 吉林省自然科学基金(批准号: 201115178)和吉林大学超分子结构与材料国家重点实验室开放课题(批准号: SKLSSM201132)资助.

Fabrication of Highly Transparent Regular Ag Arrays

JIA Ruo-Kun1, LIN Song-Zhu1, HE Ai-Min1, ZHAO Qing-Xiao1, BAI Yu-Bai2   

  1. 1. College of Chemical Engineering, Northeast Dianli University, Jilin 132012, China;
    2. College of Chemistry, Jilin University, Changchun 130012, China
  • Received:2011-10-08 Online:2012-08-10 Published:2012-08-10

摘要: 以水珠为模板制备了聚己内酯(PCL)有序多孔膜. 利用水珠在冷的高分子溶液表面凝结形成有序阵列, 溶剂蒸发后, 高分子材料按照水珠排列的形貌形成了有序多孔膜. 改变蒸发溶液的体积可得到具有透光性的有序贯通膜, 对该膜喷金后在银溶液中置换得到了有序银网阵列膜. 这种银网阵列不仅能够导电, 而且比聚己内酯阵列膜具有更高的透光性和柔韧性.

关键词: 自组装, 有序银网阵列, 透光性

Abstract: Polycaprolactam lactone(PCL) ordered porous membrane were prepared by solvent evaporation self-organization. Water drops could condenser in cold water to form regular arrays. After solvent evaporating, polymers separate and formed regular arrays on the basis of water arrays. PCL transparent films were obtained by change volume of evaporation solution. After sputtering of metal and a replacement reaction, PCL films change into Ag films. Experimental results show that the silver nets array can not only conductive than PCL array but also has higher pervious to light quality.

Key words: Self assembly, Regular Ag net array, Transparent

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