大面积多元化表面等离激元金纳米粒子结构的制备

doi:10.7503/cjcu20190658

高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (2): 221.doi: 10.7503/cjcu20190658

• 庆祝《高等学校化学学报》复刊40周年专栏 • 上一篇下一篇

大面积多元化表面等离激元金纳米粒子结构的制备

李东¹,孙迎辉²,王中舜³,黄晶¹,吕男³,江林^1,^*()

^1. 苏州大学功能纳米与软物质研究院, 苏州 215123
^2. 苏州大学能源学院, 能源与材料创新研究院, 苏州 215006
^3. 吉林大学化学学院, 长春 130012

收稿日期:2019-12-12 出版日期:2020-02-10 发布日期:2019-12-23
通讯作者: 江林 E-mail:ljiang@suda.edu.cn
基金资助:
国家自然科学基金(21822202);国家自然科学基金(21673096);国家重点研发计划项目(2016YFE0129800);国家重点研发计划项目(2018YFE0200700);国家重点研发计划项目(2018YFE0200702);江苏省碳基功能材料与器件高技术研究重点实验室开放课题(KJS1807);苏州纳米科技协同创新中心和江苏高校优势学科建设工程项目资助

Large-scale Multiplexed Surface Plasmonic Gold Nanostructures Based on Nanoimprint and Self-assembly ^†

LI Dong¹,SUN Yinghui²,WANG Zhongshun³,HUANG Jing¹,Lü Nan³,JIANG Lin^1,^*()

^1. Institute of Functional Nano & Soft Materials(FUNSOM) Laboratory, Soochow University, Suzhou 215123, China
^2. College of Energy, Institute for Energy and Materials InnovationS, Soochow University, Suzhou 215006, China
^3. College of Chemistry, Jilin University, Changchun 130012, China

Received:2019-12-12 Online:2020-02-10 Published:2019-12-23
Contact: Lin JIANG E-mail:ljiang@suda.edu.cn
Supported by:
? Supported by the National Natural Science Foundation of China(21822202);Supported by the National Natural Science Foundation of China(21673096);the National Key Research and Development Program of China(2016YFE0129800);the National Key Research and Development Program of China(2018YFE0200700);the National Key Research and Development Program of China(2018YFE0200702);the Open Project of Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, China(KJS1807);the Collaborative Innovation Center of Suzhou Nano Science & Technology, and the Priority Academic Program Development of Jiangsu Higher Education Institutions, China

摘要/Abstract

摘要：

具有显著表面等离激元共振效应的贵金属纳米粒子因其独特的光电学性质在许多领域表现出了潜在的应用价值. 结合纳米压印技术与自组装技术发展了一种高效的多元化纳米粒子结构的制备方法, 并制备了一种由不同尺寸金纳米粒子构成的周期性表面等离激元纳米粒子结构. 实验结果证明此种方法在大批量制备和结构多元化的控制方面具有独特的优势. 利用不同的表面等离激元纳米粒子结构对不同荧光分子增强效果的差异, 设计了2种具有明显明暗差异的荧光条码, 展示了多重的荧光增强响应.

关键词: 纳米压印, 自组装, 表面等离激元共振, 纳米粒子结构, 表面增强荧光

Abstract:

Noble metal nanoparticles with significant localized surface plasmon resonance effects have demonstrated potential applications in various fields due to their unique optoelectronic properties. Recently, the construction of multiplexed plasmonic nanostructures has been widely conducted. Through combining nanoimprint and self-assembly, an efficient method for the preparation of multiplexed plasmonic nanostructure with different size gold nanoparticles on a large area were developed. Meanwhile, two fluorescent barcodes were designed based on the differences in the effects of surface enhancement fluorescence, which shows a multi-functional fluorescent display.

Key words: Nanoimprint, Self-assembly, Surface plasmon resonance, Nanoparticle structure, Surface enhanced fluorescence(SEF)

中图分类号:

TrendMD:

李东,孙迎辉,王中舜,黄晶,吕男,江林. 大面积多元化表面等离激元金纳米粒子结构的制备. 高等学校化学学报, 2020, 41(2): 221.

LI Dong,SUN Yinghui,WANG Zhongshun,HUANG Jing,Lü Nan,JIANG Lin. Large-scale Multiplexed Surface Plasmonic Gold Nanostructures Based on Nanoimprint and Self-assembly ^†. Chem. J. Chinese Universities, 2020, 41(2): 221.

图/表 6

Fig.1 Schematic of preparing multiplex plasmonic lattice substrate

Fig.2 SEM images of multiplexed plasmonic substrate (A) 13 nm gold spheres assembled on the SiO2/Si substrate; (B) substrate after imprinting and oxygen plasma treatment; (C) multiplexed plasmonic nanostructures after in-situ growth; (D), (E) and (F) are amplification of (A), (B) and (C), respectively.

Fig.3 SEM section of grown nanoparticles(A) and diameter statistics of grown nanoparticles(B)

Fig.4 Electric field simulation of multiplexed nanostructure(A), experimental(B) and simulated scattering spectra(C) of different regions on multiplexed substrate

Fig.5 Surface enhanced fluorescence schematic of multiplexed substrate to HEX(A) and TEX(B), optical microscope fluorescence image of the multiplexed substrate absorbed HEX(C) and TEX(D), fluorescence spectra of the multiplexed substrate absorbed HEX(E) and TEX(F) a1 and a2 are the ratio of the fluorescence intensity for the two molecules in the growing region and the ungrowing region, respectively.

Fig.6 Emission spectra of the HEX(a) and TEX(b), and the scattering spectrum of the grown nanoparticles(c) and ungrown nanoparticles(d) The dotted lines 1 and 2 are the excitation of HEX and TEX, respectively.

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大面积多元化表面等离激元金纳米粒子结构的制备

Large-scale Multiplexed Surface Plasmonic Gold Nanostructures Based on Nanoimprint and Self-assembly ^†

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大面积多元化表面等离激元金纳米粒子结构的制备

Large-scale Multiplexed Surface Plasmonic Gold Nanostructures Based on Nanoimprint and Self-assembly †

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Large-scale Multiplexed Surface Plasmonic Gold Nanostructures Based on Nanoimprint and Self-assembly ^†