纳米氧化锰表面功能化木材的制备及性质

doi:10.7503/cjcu20170177

高等学校化学学报 ›› 2017, Vol. 38 ›› Issue (9): 1518.doi: 10.7503/cjcu20170177

• 研究论文: 无机化学 • 上一篇下一篇

纳米氧化锰表面功能化木材的制备及性质

于泽¹, 高鹤¹, 郑恺¹, 梁大鑫¹(), 刘志明¹, 庞广生², 方振兴²

1. 东北林业大学材料科学与工程学院, 哈尔滨 150040
2. 吉林大学无机合成与制备化学国家重点实验室, 长春 130012

收稿日期:2017-03-24 出版日期:2017-09-10 发布日期:2017-08-24
作者简介:联系人简介: 梁大鑫, 男, 博士, 讲师, 主要从事木材功能性改良及生物质基复合材料方面的研究. E-mail: liangdaxin@yahoo.com
基金资助:
国家自然科学基金(批准号: 31400497)、林业公益性行业科研专项重大项目(批准号: 201504602)、黑龙江省博士后基金(批准号: LBH-Z13001)、中国博士后科学基金(批准号: 2014M561311)和无机合成与制备化学国家重点实验室(吉林大学)开放课题(批准号: 2016-24)资助

Preparation and Properties of Surface Functionalized Wood by Nanoscale Manganese Oxide^†

YU Ze¹, GAO He¹, ZHENG Kai¹, LIANG Daxin^1,^*(), LIU Zhiming¹, PANG Guangsheng², FANG Zhenxing²

1. College of Materials Science and Engineering, Northeast Forestry University, Harbin 150040, China
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Received:2017-03-24 Online:2017-09-10 Published:2017-08-24
Contact: LIANG Daxin E-mail:liangdaxin@yahoo.com
Supported by:
† Supported by the National Natural Science Foundation of China(No.31400497), the Industry Research Special Funds for Public Welfare Project of China(No.201504602), the Postdoctoral Fund of Heilongjiang Province, China(No.LBH-Z13001), the China Postdoctoral Science Foundation(No.2014M561311) and the Open Project of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, China(No.2016-24)

摘要/Abstract

摘要：

采用水热反应法制备了纳米氧化锰负载木材. 通过扫描电子显微镜和能谱分析对样本进行了微观形貌和元素含量检测, 并探讨了在不同处理条件下得到的纳米氧化锰负载木材在耐腐性和抗菌性方面的表现. 数据分析显示, 氧化锰负载木材的耐腐性和抗菌性均优于未处理的木材, 水热反应中采用十二烷基硫酸钠作为表面活性剂时木材表面的氧化锰物相最纯净, 且木材样本的性能优于其它条件下制备的样本.

关键词: 纳米氧化锰, 表面功能化, 木材, 耐腐蚀性, 抗菌性

Abstract:

Nanoscale manganese oxide modified wood samples were prepared by the hydrothermal method. The morphology of the samples were observed by scanning electron microscope(SEM) and the elemental analysis of the samples was carried out by energy dispersive spectroscopy(EDS), and the corrosion resistance and antibacterial properties of the nanoscale manganese oxide modified wood under different treatment conditions were discussed. Data analysis showed that the corrosion resistance and antibacterial properties of nanoscale manganese oxide modified wood were better than those of untreated wood, and the sample treated by sodium dodecylsulfate as surfactant showed better performance on corrosion resistance and antibacterial properties than those prepared by other methods.

Key words: Nanoscale manganese oxide, Surface functionalization, Wood, Corrosion resistance, Antibacte-rial property

TrendMD:

于泽, 高鹤, 郑恺, 梁大鑫, 刘志明, 庞广生, 方振兴. 纳米氧化锰表面功能化木材的制备及性质. 高等学校化学学报, 2017, 38(9): 1518.

YU Ze, GAO He, ZHENG Kai, LIANG Daxin, LIU Zhiming, PANG Guangsheng, FANG Zhenxing. Preparation and Properties of Surface Functionalized Wood by Nanoscale Manganese Oxide^†. Chem. J. Chinese Universities, 2017, 38(9): 1518.

图/表 9

参考文献 25

[1]	Xu P. T., Build. Deco. Mater. World, 2003, Z1, 26—30
[2]	Yamamoto Y., Environ. Mater., Translated by Wang T. M., Beijing: Chemical Industry Press, 1997, 124—126
	(山本良一. 环境材料, 王天民译. 北京:化学工业出版社, 1997, 124—126)
[3]	Liu Y., Shao L., Gao J., Appl. Surf. Sci., 2015, 331, 353—361
[4]	Ansell M. P., J. Mater. Sci., 2012, 47(2), 583—598
[5]	Dan R., Ruxanda B., Carmen-Alice T., Liliana R., Cristian-Dragos V., J. Clean Prod., 2016, 112, 1157—1183
[6]	Gao H., Liang D. X., Li J., Pang G. S., Fang Z. X., Chem. J. Chinese Universities, 2016, 37(6), 1075—7081
	(高鹤, 梁大鑫, 李坚, 庞广生, 方振兴.高等学校化学学报,2016, 37(6), 1075—1081)
[7]	Wegner T. P., Jones D., Wood Fiber Sci., 2007, 37, 549—551
[8]	Wang W. D., Zhong J. L., Lu X. N., Wood Ind., 2004, 18(6), 36—37
[9]	Li L., Li J. Z., Xia S. H., China Wood-Based Panel Mag., 2007, 32(10), 35—38
[10]	Sun F. B., Yu Y., Jiang Z. H., Spectrosc. Spect. Anal., 2010, 30(4), 1056—1060
[11]	Ye J.H., Research on slice modified by nano-TiO2, Fujian Agriculture and Forestry University, Fuzhou, 2006
	(叶江华. 纳米TiO2改性薄木的研究, 福州: 福建农林大学, 2006)
[12]	Matsunaga H., Kiguchi M., Evans P. D., J. Nanopart Res., 2009, 11(5), 1087—1098
[13]	Yu W. W., Liu T. G., Cao S. Y., Wang C., Chen C. S., J. Solid State Electr., 2016, 239, 131—138
[14]	Belkhedkar M. R., Ubale A. U., Sakhare Y. S., Naushad Z., Musaddique M., Journal of the Association of Arab Universities for Basic and Applied Sciences, 2016, 21, 38—44
[15]	Qi F., Jones D., Hirofumi K., Kenta O., Manganese Oxide Porous Crystals, 1999, 9, 319—333
[16]	Du W. X., Yang J., Sang Y. X., Zhang L. L., Zhao N., Xu K., Cheng Y. N., Chem. J. Chinese Universities, 2017, 38(3), 346—354
	(杜文修, 杨娟, 桑玉祥, 张莉莉, 赵楠, 徐凯, 程晓农.高等学校化学学报,2017, 38(3), 346—354)
[17]	Pan L. J., Wang Y. B., Wang J. Q., Chinese J. Public Health Eng., 2010, 4, 243—245
	(潘力军, 王友斌, 王俊起. 中国卫生工程学, 2010, 4, 243—245)
[18]	Li S.Y., Inhibitory Effects of Heartwood Extracts form Strong Decay-resistant Tree Species on Wood Preservation., Agricultural University of Hebei Province, Baoding, 2009
	(李素英. 强耐腐性木材提取物对木材防腐作用的研究, 保定: 河北农业大学, 2009)
[19]	De Boer M., Heuer C., Hussein H., J. Dairy Sci., 2015, 98(7), 4427—4438
[20]	Pridmore A., Burch D., Lees P., Afr. J. Microbiol. Res., 2011, 511(3/4), 409—412
[21]	Bruin J. P., Diederen B. M. W., Ijzerman E. P. F., Diagn. Micr. Infec. Dis., 2013, 76(3), 339—342
[22]	Wang Y. B., Pan L. J., Xue J. R., Chinese J. Public Health Eng., 2010, 6, 403—405
	(王友斌, 潘力军, 薛金荣. 中国卫生工程学, 2010, 6, 403—405)
[23]	Meng Y. J., Liu X. Y., Liu L., Li B. X., Zhao X. D., Feng L. K., Wang Y. X., Wang X. F., Chem. Res. Chinese Universities, 2015, 31(5), 820—824
[24]	Zhang X.H., Microwave-Assisted Hydrothermal Synthesis of MnO2 with Controlled Morphology and Its Electrochemical Properties, Jilin University, Changchun, 2013
	(张欣皓. 微波辅助水热条件下形貌可控二氧化锰的合成及其电化学性质的研究, 长春: 吉林大学, 2013)
[25]	Ding X. C., Dana L., Laurent M., Carbohydrate Polymers, 2011, 86(1), 58—64

Grade	Broad-leaved wood mass loss rate(%)	Coniferous wood mass loss rate(%)
(Ⅰ) Most resistant to rot	0—10	0—10
(Ⅱ) Corrosion resistance	11—30	11—20
(Ⅲ) Slightly resistant rot	31—50	21—30
(Ⅳ) No decay resistance	>50	>30

Grade	Broad-leaved wood mass loss rate(%)	Coniferous wood mass loss rate(%)
(Ⅰ) Most resistant to rot	0—10	0—10
(Ⅱ) Corrosion resistance	11—30	11—20
(Ⅲ) Slightly resistant rot	31—50	21—30
(Ⅳ) No decay resistance	>50	>30

Sample	M/g	N/g	Mass loss rate(%)	Corrosion resistance grade
Blank	0.1104	0.0643	41.7572	Ⅲ
1	0.1265	0.0823	34.9407	Ⅲ
2	0.1229	0.0811	34.0114	Ⅲ
3	0.1301	0.0828	36.3566	Ⅲ
4	0.1125	0.0754	32.9778	Ⅲ
5	0.1276	0.0833	34.7179	Ⅲ
6	0.1198	0.0802	33.0551	Ⅲ

Sample	M/g	N/g	Mass loss rate(%)	Corrosion resistance grade
Blank	0.1104	0.0643	41.7572	Ⅲ
1	0.1265	0.0823	34.9407	Ⅲ
2	0.1229	0.0811	34.0114	Ⅲ
3	0.1301	0.0828	36.3566	Ⅲ
4	0.1125	0.0754	32.9778	Ⅲ
5	0.1276	0.0833	34.7179	Ⅲ
6	0.1198	0.0802	33.0551	Ⅲ

Sample	M/g	N/g	Mass loss rate(%)	Corrosion resistance grade
Blank	0.1214	0.0671	44.7282	Ⅳ
1	0.159	0.1397	12.1384	Ⅱ
2	0.1687	0.1454	13.8115	Ⅱ
3	0.1702	0.1412	17.0388	Ⅱ
4	0.1761	0.1441	18.1715	Ⅱ
5	0.1723	0.1448	15.9605	Ⅱ
6	0.1607	0.1455	9.4586	Ⅰ

纳米氧化锰表面功能化木材的制备及性质

Preparation and Properties of Surface Functionalized Wood by Nanoscale Manganese Oxide^†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 25

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李华, 杨科, 黄俊峰, 陈凤娟. UiO-66-NH₂/wood的设计构筑及高效去除水中微量重金属离子性能[J]. 高等学校化学学报, 2022, 43(3): 20210701.
[2]	艾翠玲, 吴丽娜, 张嵘嵘, 邵享文, 许俊鸽. γ-Fe₂O₃/Ag/TiO₂的制备与抗菌性能[J]. 高等学校化学学报, 2019, 40(4): 645.
[3]	谢超, 洪国辉, 杨伟强, 王继库, 赵丽娜. 利用蜡烛灰制备超疏水疏油抗菌涂层[J]. 高等学校化学学报, 2019, 40(2): 379.
[4]	袁宝明,董晓明,杨帆,彭传刚,王金成,吴丹凯. 载银离子PLGA-PEG-PLGA温度敏感水凝胶的制备及体外抗菌性能[J]. 高等学校化学学报, 2019, 40(10): 2225.
[5]	殷茂力, 王英沣, 任学宏. 改性壳聚糖抗菌纳米微球的制备[J]. 高等学校化学学报, 2019, 40(1): 173.
[6]	董晓明, 袁宝明, 陈炳鹏, 贺超良, 王金成, 陈学思. 载万古霉素PLGA-PEG-PLGA温度敏感水凝胶的体外抗菌性能[J]. 高等学校化学学报, 2017, 38(5): 866.
[7]	李会, 邢哲, 李荣, 张明星, 王明磊, 谭奕哲, 吴国忠. 高效抗菌Cu²⁺-壳聚糖季铵盐/丙烯酸复合物的制备[J]. 高等学校化学学报, 2017, 38(5): 902.
[8]	杜文修, 杨娟, 桑玉祥, 张莉莉, 赵南, 徐凯, 程晓农. Ag/Fe₃O₄/rGO纳米复合材料的制备及抗菌性能[J]. 高等学校化学学报, 2017, 38(3): 346.
[9]	付冉冉, 纪秀杰, 刘超, 任燕飞, 汪港, 程博闻. 离子液体中纤维素/纳米层状ZnO复合抗菌纤维的制备及性能[J]. 高等学校化学学报, 2017, 38(12): 2344.
[10]	陈华军, 席晓晶, 丁梧秀. 银掺杂介孔氧化铝抗菌剂的一步合成与表征[J]. 高等学校化学学报, 2016, 37(6): 1036.
[11]	李霞, 曹义鸣, 康国栋, 于海军, 刘中楠. 基于多巴胺自聚合与表面接枝PHGH制备抗菌纳滤膜[J]. 高等学校化学学报, 2014, 35(9): 2026.
[12]	彭俊军, 张馨, 吴毅明, 刘红玲, 冉建华, 李明, 杨锋. 壳聚糖改性织物中原位合成银纳米粒子[J]. 高等学校化学学报, 2014, 35(2): 415.
[13]	潘琰, 关爽, 郭玉鹏, 刘志辉. Ag/AgNO₃修饰钛酸盐纳米管薄膜的制备及性能[J]. 高等学校化学学报, 2013, 34(9): 2068.
[14]	刘伟, 赵莹, 余泽华, 李文兰, 万晓巧. 杂环-双氰乙基系列分散染料的合成、表征及染色性能[J]. 高等学校化学学报, 2013, 34(3): 590.
[15]	张宝亮, 张秋禹, 张和鹏, 刘瑜, 范新龙, 许海龙. 负载高密度乙肝检测探针磁珠的制备及性能[J]. 高等学校化学学报, 2011, 32(5): 1070.

Sample	Against E. coli	Against Staphylococcus aureus	Sample	Against E. coli	Against Staphylococcus aureus
Blank	0	0	5	25	24
1	18	22	6	15	13
2	21	22	7	12	12
3	20	23	8	29	28
4	20	19

Sample	Against E. coli	Against Staphylococcus aureus	Sample	Against E. coli	Against Staphylococcus aureus
Blank	0	0	5	25	24
1	18	22	6	15	13
2	21	22	7	12	12
3	20	23	8	29	28
4	20	19

纳米氧化锰表面功能化木材的制备及性质

Preparation and Properties of Surface Functionalized Wood by Nanoscale Manganese Oxide†

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 25

相关文章 15

编辑推荐

Metrics

本文评价

Preparation and Properties of Surface Functionalized Wood by Nanoscale Manganese Oxide^†