高等学校化学学报

高等学校化学学报 ›› 2011, Vol. 32 ›› Issue (8): 1876.

• 研究论文 • 上一篇    下一篇

介孔碳纳米纤维为载体的铂催化剂的制备及电化学性质

杨桦,孙德慧,任慧娟,崔振峰   

  1. 长春工程学院理学院, 长春 130012
  • 收稿日期:2010-08-26 修回日期:2011-01-01 出版日期:2011-08-10 发布日期:2011-07-19
  • 通讯作者: 杨桦 E-mail:yanghua123@gmail.com
  • 基金资助:

    吉林省教育厅科学基金(批准号:  2008371)资助.

Preparation and Electrochemical Properties of Pt-catalysts Supported on Mesoporous Carbon Nanofibers

YANG Hua*, SUN De-Hui, REN Hui-Juan, CUI Zhen-Feng   

  1. School of Science, Changchun Institute of Technology, Changchun 130012, China
  • Received:2010-08-26 Revised:2011-01-01 Online:2011-08-10 Published:2011-07-19
  • Contact: YANG Hua E-mail:yanghua123@gmail.com
  • Supported by:

    吉林省教育厅科学基金(批准号:  2008371)资助.

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被引次数

5

摘要： 本文利用介孔碳的软模板合成方法和阳极氧化铝膜的孔道限域性制备有序的介孔碳纳米纤维。然后以介孔碳纳米纤维作载体，采用温和的非共价方法和乙二醇还原法负载铂纳米粒子来制备铂催化剂。实验结果表明，温和的功能化方法有利于载体介孔结构的保持和铂纳米粒子的分散，并且还原反应条件对铂纳米粒子的负载具有重要影响。最后通过循环伏安法研究了铂催化剂的电化学性质，结果表明这些铂催化剂具有良好的甲醇电催化活性和稳定性。

关键词: 介孔碳纳米纤维, 铂催化剂, 电催化

Abstract: Ordered mesoporous carbon nanofibers were prepared by combining the soft template synthesis method of mesoporous carbons with the confinement of channels of anode alumina membranes. The ordered mesoporous carbon nanofibers as supports for loading Pt nanoparticles were obtained using a noncovalent method and ethylene glycol reduction. The results indicate that the mild functionalization method is beneficial for conservation of mesostructure of supports and distribution of Pt nanoparticles. Moreover, the condition of reduction is very important for the load of Pt nanoparticles. The electrochemical properties were studied by cyclic voltammogram and the results show that the Pt-catalysts possess excellent methanol electrocatalytic activity and stability.

Key words: Mesoporous carbon nanofiber, Pt-catalyst, Electrocatalysis

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