高等学校化学学报

高等学校化学学报 ›› 2011, Vol. 32 ›› Issue (3): 678.

• 研究论文 • 上一篇    下一篇

微波辅助溶剂热法合成烟酸锌配位聚合物

高飞,王颖,刘晓旸   

  1. 吉林大学化学学院,  无机合成与制备化学国家重点实验室,  长春 130012
  • 收稿日期:2010-09-27 修回日期:2010-12-08 出版日期:2011-03-10 发布日期:2011-02-23
  • 通讯作者: 刘晓旸 E-mail:liuxy@jlu.edu.cn
  • 基金资助:

    国家自然科学基金(批准号: 40673051)资助.

Microwave-assisted Solvothermal Synthesis of Bis(nicotinate)zinc

GAO Fei, WANG  Ying, LIU Xiao-Yang*   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012,  China
  • Received:2010-09-27 Revised:2010-12-08 Online:2011-03-10 Published:2011-02-23
  • Contact: Xiao-Yang LIU E-mail:liuxy@jlu.edu.cn
  • Supported by:

    国家自然科学基金(批准号: 40673051)资助.

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被引次数

8

摘要： 首次利用微波辅助溶剂热法，10min便成功地合成了烟酸锌配位聚合物并对其性质进行了表征。讨论了时间、温度、底物浓度、加热方法及溶剂等因素对产物结晶情况和晶体粒径大小的影响；将微波溶剂热与传统溶剂热法相结合，得到的产物既具备了微波加热反应速度快、晶体成核均匀等优点，同时也得到了较大的单晶体并对其进行了晶体结构解析。

关键词: 微波, 溶剂热, 烟酸锌, 晶体

Abstract: Bis(nicotinate)zinc was successfully synthesized under microwave-assisted solvothermal condition and the influences of reaction time, temperature, solvent, substrate concentration and heating method on the crystallization of the complexes were disscussed. With combination of the microwave-assisted solvothermal method and the conventional solvothermal method, the product so obtained not only has the advantages of microwave heating, but also has a large particle size that suitable for structural analysis.

Key words: Microwave, Solvothermal, Bis(nicotinate)zinc, Crystal

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