高等学校化学学报

高等学校化学学报

• 研究论文 • 上一篇    下一篇

钌卟啉轴向配合物的合成与结构表征

鲍小平1; 王磊1; 王凯1; 张智1; 郭建平2; 李早英1   

  1. 1. 武汉大学化学与分子科学学院, 武汉 430072;
    2. 香港浸会大学化学系, 香港
  • 收稿日期:2005-11-10 修回日期:1900-01-01 出版日期:2006-07-10 发布日期:2006-07-10
  • 通讯作者: 李早英

Synthesis and Structure Characterization of Ruthenium Porphyrin Axial Complexes

BAO Xiao-Ping1; WANG Lei1; WANG Kai1; ZHANG Zhi1; GUO Jian-Ping2; LI Zao-Ying1*

  

  1. 1. College of Chemistry and Molecular Sciences, Wuhan University,
    Wuhan 430072, China;
    2. Department of Chemistry, Hong Kong Baptist University, Hong Kong, China
  • Received:2005-11-10 Revised:1900-01-01 Online:2006-07-10 Published:2006-07-10
  • Contact: LI Zao-Ying

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被引次数

5

摘要： 采用一种简单的合成方法, 以钌羰基卟啉(1)和二氧钌卟啉(2)为原料, 与不同的氨基酸酯作用, 得到系列单氨基酸酯羰基和双氨基酸酯为轴向配体的钌卟啉配合物(4a~4c和5a~5d). 所有化合物均经过红外光谱、 核磁共振谱和质谱等表征手段确证为目标化合物, 并用X射线单晶衍射测定了化合物4a的分子结构, 这对研究钌卟啉与生物大分子的相互作用具有重要的意义.

关键词: 钌卟啉, 合成, 结构表征, 晶体结构

Abstract: A simple synthetic method was described i.e., via the reaction of ruthenium carbonylporphyrin(1) and dioxygenruthenium porphyrin(2) with different aminocarboxylates, a series of ruthenium porphyrins(4a-4c and 5a-5d) with monoaminocarboxylate carbonyl and diaminocarboxylates as axial ligands were obtained respectively. All compounds were confirmed by IR, 1H NMR, MS spectra and the molecular structure of compound(4a) was determined by X-ray singlecrystal diffraction. This study will provide significant help for investigations on interactions between mthenium porphyrin and biomicromolecules.

Key words: Ruthenium porphyrin, Synthesis, Structure characterization, Crystal structure

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