高等学校化学学报

高等学校化学学报 ›› 2004, Vol. 25 ›› Issue (2): 354.

• 研究简报 • 上一篇    下一篇

在SO42-/ZrO2-MCM-41上苯与丙烯的烷基化

魏长平1, 王伟东2, 邵晶1, 甄开吉2   

  1. 1. 长春理工大学材料与化工学院, 长春 130022;
    2. 吉林大学化学学院, 长春 130023
  • 收稿日期:2003-02-24 出版日期:2004-02-24 发布日期:2004-02-24
  • 通讯作者: 魏长平(1960年出生),女,博士,教授,从事多孔材料与新材料制备、材料改性与应用研究.E-mail;changpingwei@hotmail.com E-mail:changpingwei@hotmail.com
  • 基金资助:

    国家留学基金委(CSC);教育部留学归国人员科研启动基金资助

Alkylation of Benzene with Propene over SO42-/ZrO2-MCM-41 Catalyst

WEI Chang-Ping1, WANG Wei-Dong2, SHAO Jing1, ZHEN Kai-Ji2   

  1. 1. College of Materials and Chemical Engineering, Changchun University of Science and Technology, Changchun 130022, China;
    2. College of Chemistry, Jilin University, Changchun 130023, China
  • Received:2003-02-24 Online:2004-02-24 Published:2004-02-24

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关键词: 苯, 丙烯, 异丙苯, SO42-/ZrO2-MCM-41催化剂

Abstract: Super acid catalyst SO42-/ZrO2 was introduced in pure silicone MCM-41 by macerating method and characterized by XRD, IR and Py-IR. The selectively catalytic gas phase flow reaction of benzene and propene over the catalysts was tested. The result show that the SO2-4/ZrO2-MCM-41(SZM-41) can be used as a catalyst for the title reaction and has a high catalytic activity under some conditions.

Key words: Benzene, Propene, iso-Propyl benzene, SO42-/ZrO2-MCM-41 catalyst

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