高等学校化学学报 ›› 2003, Vol. 24 ›› Issue (7): 1161.

• 论文 • 上一篇    下一篇

噻唑取代的新氮氧自由基NIT2-thz及其配合物Ni(NIT2-thz)2Cl2的合成、晶体结构和磁性

王利亚1, 杨和平1, 廖代正1, 姜宗慧1,2, 阎世平1   

  1. 1. 南开大学化学系, 天津 300071;
    2. 南京大学配位化学国家重点实验室, 南京 210093
  • 收稿日期:2002-12-24 出版日期:2003-07-24 发布日期:2003-07-24
  • 通讯作者: 姜宗慧(1940年出生),女,教授,博士生导师,从事功能配合物化学研究.E-mail:coord@nankai.edu.cn E-mail:coord@nankai.edu.cn
  • 基金资助:

    国家自然科学基金(批准号:20171025,90101028)资助

Synthesis, Crystal Structure and Magnetic Properties of Ni(Ⅱ) Complex with a New Thiazole-substituted Nitronyl Nitroxide

WANG Li-Ya1, YANG He-Ping1, LIAO Dai-Zheng1, JIANG Zong-Hui1,2, YAN Shi-Ping1   

  1. 1. Department of Chemistry, Nankai University, Tianjin 300071, China;
    2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China
  • Received:2002-12-24 Online:2003-07-24 Published:2003-07-24

关键词: 噻唑自由基, Ni(Ⅱ)配合物, 晶体结构, 磁性

Abstract: A new nickl(Ⅱ) complex containing the thiazole-substituted nitroxide radical with the formula Ni(NIT2-thz)2Cl2(NIT2-thz=4,4,5,5-tetramethyl-2-(2′-thiazole)imidazolin-1-oxyl-3-oxide) was synthesized and its crystal structure was determined. The magnetic property analysis indicates that there is strong antiferromagnetic interactions between Ni(Ⅱ) and radical(J=-71.82cm-1).

Key words: Thiazole nitroxide radical, Ni(Ⅱ) complex, Crystal structure, Magnetism

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