高等学校化学学报

高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (8): 1480.

• 研究快报 • 上一篇    下一篇

具有八-环开放骨架结构的Ni3(PO4)2·8H2O的水热合成与表征

李亚丰, 崔巍, 朱广山, 裘式纶, 方千荣, 王春雷   

  1. 吉林大学无机合成与制备化学国家重点实验室, 长春 130023
  • 收稿日期:2002-01-28 出版日期:2002-08-24 发布日期:2002-08-24
  • 作者简介:裘式纶(1948年出生),男,博士,教授,博士生导师,从事无机化学研究.
  • 基金资助:

    国家重大基础研究项目(批准号:G2000077507)资助

Hydrothermal Synthesis and Characterization of Ni3(PO4)2·8H2O with8-Ring and4-Ring Network Structure

LI Ya-Feng, CUI Wei, ZHU Guang-Shan, QIU Shi-Lun, FANG Qian-Rong, WANG Chun-Lei   

  1. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2002-01-28 Online:2002-08-24 Published:2002-08-24

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关键词: 水热合成, 晶体, 结构

Abstract: Anew two dimensional 8-ring network nickle phosphate Ni3(PO4)2·8H2Owas synthesized hydrothermally and its structure was determined by means of single-crystal X-ray diffraction. The Ni3(PO4)2·8H2Ocrystal crystallizes in the monoclinic system, space group C2/m, with M=128.13, a=0.9947(2) nm, b=1.3217(3)nm; c=0.4636(1) nm; β=104.80(3)°, V=0.5893(2) nm3, Z=2, R=0.0272 and wR=0.0575. The network structure consists of vertex sharing which results in the formation of undulating 4-ring chains and 8-ring sheets.

Key words: Hydrothermal synthesis, Crystal, Structure

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