高等学校化学学报 ›› 2002, Vol. 23 ›› Issue (10): 1854.

• 研究快报 • 上一篇    下一篇

具有四帽假Keggin结构“簇阴离子对”的多金属氧簇[Co(2,2-bipy)3]4[Mo5Mo5V6O40(PO4)]2·4H2O的水热合成与晶体结构

曾庆新1, 吕高孟3, 李亚丰2, 杨国昱1, 徐吉庆2   

  1. 1. 中国科学院福建物质结构研究所结构化学国家重点实验室, 配位与水热化学研究组, 福州 350002;
    2. 吉林大学化学学院, 长春 130023;
    3. 中国科学院兰州化学物理研究所, 兰州 730000
  • 收稿日期:2001-12-31 出版日期:2002-10-24 发布日期:2002-10-24
  • 通讯作者: 杨国昱(1965年出生),男,博士,研究员,博士生导师,从事无机化学、材料化学和固态化学等方面研究.
  • 基金资助:

    国家自然科学基金(批准号:20171045);国家财政部基金;中国科学院“引进国外杰出人才”专项基金;高等学校博士学科点专项科研基金资助

Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)3]4[Mo5Mo5V6O40(PO4)]2·4H2O Containing Double Tetracapped Pseudo-Keggin Cluster Anions

ZENG Qing-Xin1, LÜ Gao-Meng3, LI Ya-Feng2, YANG Guo-Yu1, XU Ji-Qing2   

  1. 1. Coordination and Hydrothermal Chemistry Group, State Key Laboratory of the Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
    2. College of Chemistry, Jilin University, Changchun 130023, China;
    3. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
  • Received:2001-12-31 Online:2002-10-24 Published:2002-10-24

关键词: 水热合成, 假Keggin结构, 晶体结构

Abstract: The title compound[Co(2,2-bipy)3]4[Mo10V6O40(PO4)]2·4H2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a=316 5(3)nm, b=1.438 2(3) nm, c=2.764 4(6) nm, α=79.51°, β=89.95°, γ=68.89°, V=4.789 3(17)nm3, Z=1, Dc=2.176 g/cm3, R=0.075 5, wR=0.205 3, S=0.995.

Key words: Hydrothermal synthesis, Pseudo-Keggin, Crystal structure

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