高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (9): 1601.

• 研究论文 • 上一篇    下一篇

锇-聚乙烯吡啶复合物与辣根过氧化物酶分子多层膜的制备及其电化学性质研究

李文江1, 宋利珠1, 孙长青1, 王子忱1, 郭玉鹏1, 赵纯1, 徐英凯2   

  1. 1. 吉林大学化学系, 长春 130023;
    2. 中国科学院化学研究所, 北京 100080
  • 收稿日期:2000-03-31 出版日期:2001-09-24 发布日期:2001-09-24
  • 通讯作者: 赵　纯(1966年出生),男,博士,副教授,主要从事纳米功能材料的制备与组装研究.
  • 基金资助:

    吉林省自然科学基金资助

Preparation of Ultrathin Multilayer Films Containing Poly(4-vinylpyridine) Complex of Osmium and Horseradish Peroxidase and Its Electrochemical Behavior

LI Wen-Jiang1, SONG Li-Zhu1, SUN Chang-Qing1, WANG Zi-Chen1, GUO Yu-Peng1, ZHAO Chun1, Xu Ying-kai2   

  1. 1. Department of Chemistry, Jilin University, Changchun 130023, China;
    2. Instituteof Chemistry, the Chinese Academy of Sciences, Beijing 100080, China
  • Received:2000-03-31 Online:2001-09-24 Published:2001-09-24

PDF (PC)

被引次数

18

摘要： 基于分子间静电相互作用力,将锇-聚乙烯吡啶复合物(PVP-Os)与辣根过氧化物酶(HRP)交替沉积于固体基质表面,制得了包含生物成分的分子多层膜.膜层间的聚合物分子起到了粘接与导电的双重作用.用紫外-可见光谱法跟踪了石英基片上的组装过程,研究了多层膜电极对过氧化氢的电催化还原性能,并描述了多层膜电化学行为.

关键词: 锇-聚乙烯吡啶复合物, 辣根过氧化物酶, 分子多层膜, 电催化, 自组装

Abstract: We prepared a new kind of multilayer films based on ionic self-assembly technique by successive alternating deposition of positively charged polycation bearing Os complex(PVP-Os) and horseradish peroxidase(HRP) on the surface modified of gold electrode to study the electrochmical behavior and quartz slides to monitor the assembly process by ultraviolet-visible spectroscopy. The electrochemical behavior of the enzyme electrode showed that the multilayer films were stable, electroactive, the mediator PVP-Os as electron shuttle was able to transfer electrons successfully between the active center of the immobilized HRPand the electrode surface.

Key words: Poly(4-vinylpyridine) complex of Osmium, Horseradish peroxidase, Molecular multilayer, Electrical catalysis, Self-assembly

中图分类号: 

TrendMD: