高等学校化学学报

高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (9): 1450.

• 研究快报 • 上一篇    下一篇

一种新型杂化单晶[Ga3(PO4)3F2]H3O·(H3NCH2CH2)2NH2的合成与结构表征

姚有为1, 赵永男2, 乐善堂1, 徐恒连1, 梁宏斌3, 赵大庆1   

  1. 1. 中国科学院长春应用化学研究所, 稀土化学与物理开放实验室, 长春 130022;
    2. 中国科学院北京物理研究所, 凝聚态物理研究中心, 北京 100080;
    3. 黑龙江省科学院技术物理研究所, 哈尔滨 150086
  • 收稿日期:2001-06-04 出版日期:2001-09-24 发布日期:2001-09-24
  • 通讯作者: 赵大庆(1963年出生),男,博士,研究员,从事微孔材料合成及生物无机化学研究.

Synthesis and Characterization of a Novel Hybrid Single Crystal [Ga3(PO4)3F2]H3O·(H3NCH2CH2)2NH2

YAO You-Wei1, ZHAO Yong-Nan2, YUE Shan-Tang1, XU Heng-Lian1, LIANG Hong-Bin3, ZHAO Da-Qing1   

  1. 1. Department of Chemical Engineering;
    2. Department of Chemistry, Northwest University, Xi'an 710069, China
  • Received:2001-06-04 Online:2001-09-24 Published:2001-09-24

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关键词: 磷酸镓, 水热合成, 二乙烯三胺

Abstract: Anovel three dimensional fluorinated gallium-phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X-ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a=1.6056(7) nm, b=10114 (4) nm, c=1.8546(5) nm, V=3.0116(19) nm3, Z=4. The three dimensional framework based on linkage of corner sharing polyhedron PO4, GaO4Fand GaO4F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.

Key words: Gallium-phosphate, Hydrothermal synthesis, Diethylenetriamine

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