高等学校化学学报 ›› 2001, Vol. 22 ›› Issue (4): 695.

• 研究快报 • 上一篇    下一篇

含稀土铽(Ⅲ)配合物透明树脂的制备及性能研究

王冬梅1, 林权1, 符连社2, 李焕荣2, 储振兴1, 杨柏1   

  1. 1. 超分子结构与谱学教育部重点实验室, 吉林大学化学系, 长春 130023;
    2. 中国科学院长春应用化学研究所稀土化学与物理开放实验室, 长春 130022
  • 收稿日期:2000-09-14 出版日期:2001-04-24 发布日期:2001-04-24
  • 通讯作者: 杨柏(1962年生),男,博士,教授,博士生导师,主要从事功能性及高性能聚合物光学材料研究.
  • 基金资助:

    国家自然科学基金(批准号:29925412)资助

The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex

WANG Dong-Mei1, LIN Quan1, FU Lian-She2, LI Huan-Rong2, CHU Zhen-Xing1, YANG Bai1   

  1. 1. Key Laboratory of Supramolecular Structureand Spectroscopyof Educational Ministry, Depa rtment of Chemistry, Jilin University, Changchun 130023, China;
    2. Changchun Institute of Applied Chemistry, State Kay Laboratoryof Rare Earth Chemistry and Physics, Chinese Academy of Sciences, Changchun 130022, China
  • Received:2000-09-14 Online:2001-04-24 Published:2001-04-24

关键词: 透明树脂, 稀土配合物, 光学性质

Abstract: The binary and ternary rare earth terbium(Ⅲ) complexes were introduced into the styrene/ α methylacrylic acid copolymerization system, and some optical resins that possess a high transparency in visible light region were obtained. The study of the optical property showed that they have good luminescent properties such as a high luminous intensity and a long luminous lifetime. In addition, we investigated the relationship among the transparency, the luminescent property of the copolymer, and the content of the components in the polymeric system. The results indicated that the optical resins can provide a relatively stable environment for composite rare earth complexes, which is good to exhibit the luminescent properties of rare earth complexes. At the same time, the rare earth complexes can offer the transparent resin a novel function.

Key words: Transparent resin, Rare earth complex, Optical property

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