高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (10): 1538.

• 论文 • 上一篇    下一篇

静电离子色谱用于硼酸溶液中硼不同形态组分分离的研究

申贵隽, 彭增辉, 黄海英, 师宇华, 于爱民, 金钦汉   

  1. 吉林大学化学系, 长春 130023
  • 收稿日期:1999-02-05 出版日期:1999-10-24 发布日期:1999-10-24
  • 通讯作者: 金钦汉
  • 作者简介:申贵隽,男,41岁,硕士研究生.
  • 基金资助:

    国家自然科学基金(批准号:29675006)资助课题

Studies on Separation of Different Species Containing Boron in Boric Acid Solution Using Electrostatic Ion Chromatography

SHEN Gui-Jun, PENG Zeng-Hui, HUANG Hai-Ying, SHI Yu-Hua, YU Ai-Min, JIN Qin-Han   

  1. Department of Chemistry, Jilin University, Changchun 130023, China
  • Received:1999-02-05 Online:1999-10-24 Published:1999-10-24

摘要: 改进了把胆汁酸诱导体胶束(CHAPSO)涂覆在ODS载体上制备静电离子色谱固定相的方法.以纯水为流动相,采用示差折光检测器,研究了硼酸溶液中硼的形态、分离条件,并对色谱峰进行了解析.此外,还对硼酸溶液中硼离子、硼分子的色谱保留行为进行了探讨.

关键词: 静电离子色谱, 硼, 硼酸溶液, 形态, 保留行为

Abstract: Astationary phase for the electrostatic ion chromatography(EIC) was improved by coating the reversed-phase ODS column with conjugated bile acid salt micelles(CHAPSO). The detector of refactometry was connected on line to the EIC. Using purewater as mobile phase, the separation and speciation conditions of species in boric acid solution were studied. Retention behavior of EICfor ions and molecules in boric acid solutions were discussed.

Key words: Electrostatic ion chromatography, Boron, Boric acid solution, Speciation, Re-tention behavior

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