高等学校化学学报 ›› 2020, Vol. 41 ›› Issue (7): 1426-1448.doi: 10.7503/cjcu20200090

• 庆祝《高等学校化学学报》复刊40周年专栏 • 上一篇    下一篇

催化不对称碳硼成键反应研究进展

黄明耀,朱守非*()   

  1. 南开大学化学学院, 元素有机化学研究所, 天津 300071
  • 收稿日期:2020-02-20 出版日期:2020-07-10 发布日期:2020-04-08
  • 通讯作者: 朱守非 E-mail:sfzhu@nankai.edu.cn
  • 基金资助:
    国家自然科学基金(21625204);国家自然科学基金(21971119)

Recent Advances of Catalytic Asymmetric C—B Bond Forming Reactions

HUANG Mingyao,ZHU Shoufei*()   

  1. State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
  • Received:2020-02-20 Online:2020-07-10 Published:2020-04-08
  • Contact: Shoufei ZHU E-mail:sfzhu@nankai.edu.cn
  • Supported by:
    † National Natural Science Foundation of China(21625204);National Natural Science Foundation of China(21971119)

摘要:

从不对称催化的角度总结了近年来碳硼成键反应的研究进展, 评述了这些反应各自的特点, 并对其未来研究进行了展望.

关键词: 手性有机硼, 不对称催化, 碳硼成键反应

Abstract:

Organoboron compounds are of particular importance in the fields of synthesis, pharmaceutical and material sciences. With retention of the absolute configuration, a boryl group can be easily transformed into another functional group, which make chiral organoborons versatile reagents in synthetic chemistry. On the other side, chiral organoborons can serve as drugs or bioactive molecules and applied for the diagnosis and treatment of many diseases. Given these functions, methods for the synthesis of chiral organoboron compounds are intensively investigated in the field of organic synthesis. Herein, we reviewed the recent progresses on the catalytic asymmetric C—B bond forming reactions.

Key words: Chiral organoboron, Asymmetric catalysis, C—B bond formation

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