高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (4): 560.

• 论文 • 上一篇    下一篇

单臂冠醚结构与液晶性质

蒋青, 谢明贵, 李龙章, 阮继武, 王学军   

  1. 四川联合大学化学系, 成都, 610064
  • 收稿日期:1997-04-11 出版日期:1998-04-24 发布日期:1998-04-24
  • 通讯作者: 谢明贵
  • 作者简介:蒋青,男,34岁,副教授.
  • 基金资助:

    国家自然科学基金

Structures and Mesomorphic Properties of Monoarmed Crown Ether Liquid Crystals

JIANG Qing, XIE Ming-Gui, LI Long-Zhang, RUAN Ji-Wu, WANG Xue-Jun   

  1. Department of Chemistry, Sichuan United University, Chengdu, 610064
  • Received:1997-04-11 Online:1998-04-24 Published:1998-04-24

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摘要： 设计并合成了4个单臂冠醚液晶,考察了冠醚环与亲酯性结构单元之间的桥键与液晶性质的关系,中心桥键对单臂冠醚液晶的熔点影响不大,而对液晶热稳定性有较大的影响.

关键词: 冠醚液晶, 液晶性质, 结构

Abstract: Four monoarmed crown ether liquid crystals were designed and synthesized. The relationship between the properties of liquid crystal and central bridge bond that contact the crown ether and lipophilic structural unit was investigated. The melting point of crown ether liquid crystals was changed a little by variation central bridged bond. The various central bridged bonds change the stability of liquid crystalline phase. The order of clearing point is _N＝CH_ > _N＝N_ > _O_CO_ > _HN_CO_.

Key words: Crown ether liquid crystals, Liquid crystalline properties, Structures

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