高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (1): 24.

• 研究简报 • 上一篇    下一篇

1-苯基-3-甲基-4-苯甲酰基吡唑啉酮-5与胺类缔合研究

杨永会1, 宋其圣1, 田昕1, 孙思修1, 薛淑云2   

  1. 1. 山东大学化学院, 济南, 250100;
    2. 青岛大学师范学院化学系, 青岛, 266071
  • 收稿日期:1996-12-31 出版日期:1998-01-24 发布日期:1998-01-24
  • 通讯作者: 孙思修
  • 作者简介:杨永会,男,33岁,副教授.
  • 基金资助:

    国家自然科学基金(2961022)和化学工程联合国家重点实验室资助课题.

Studies on the Association of HPMBP with Some Amine Extractants

YANG Yong-Hui1, SONG Qi-Sheng1, TIAN Xin1, SUN Si-Xiu1, XUE Shu-Yun2   

  1. 1. Department of Chemistry, Shandong University, Jinan, 250100;
    2. Department of Chemistry, Normal College, Qingdao University, Qingdao, 266071
  • Received:1996-12-31 Online:1998-01-24 Published:1998-01-24

关键词: 1-苯基-3-甲基-4-苯甲酰基吡唑啉酮-5, 缔合效应,

Abstract: Studies on association effect of HPMBP and different amine extractants (N1923,DOA, TOA) in benzene and association constents of HPMBP and TOA in different diluents were carried out. The association compounds of TOA and amine extractants exist widely,which were associated through hydrogen bond into 1: 1 compounds. The order of association ability (TOA>DOA>N1923) was consistent to their extraction abilities. Therefore, in different diluents, the association order of HPMBP and TOA was toluene>cyclohexane>n-hexane>benzene.

Key words: 1-Phenyl-3-methyl-4-benzoylpyrazolone-5, Association effect, Amine

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