高等学校化学学报

高等学校化学学报 ›› 1998, Vol. 19 ›› Issue (1): 21.

• 研究简报 • 上一篇    下一篇

(Na[Fe(CO)2C5H5]2)n的形成和反应特性的研究

阎鹏飞1, 高金胜1, 乐征宇1, 毛桂杰2   

  1. 1. 黑龙江大学化学系, 哈尔滨, 150080;
    2. 黑龙江大学分析测试中心, 哈尔滨, 150080
  • 收稿日期:1996-09-03 出版日期:1998-01-24 发布日期:1998-01-24
  • 通讯作者: 高金胜
  • 作者简介:阎鹏飞,男,42岁,副教授.
  • 基金资助:

    黑龙江省自然科学基金资助课题.

Studies on the Formation and Reactivity of(Na[Fe(CO)2C5H5]2)n

YAN Peng-Fei1, GAO Jin-Sheng1, LE Zheng-Yu1, MAO Gui-jie2   

  1. 1. Department of Chemistry, Heilongjiang University, Harbin, 150080;
    2. The Center of Analysis and Testing, Heilongjiang University, Harbin, 150080
  • Received:1996-09-03 Online:1998-01-24 Published:1998-01-24

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关键词: 多聚双环戊二烯基二羰基铁钠, 反应特性, 异核金属配合物

Abstract: According to the reaction of [Fe(CO)2C5H5]2 with sodium amalgam (Na/Hg), the molecular structures of crystals and the IR data of L3SnFe (CO)2C5H5 (L=C6H11, C6H5),[ (C5Me5)2Ln (CO)2FeC5H5]2(Ln=Dy, Gd, Sm, Nd, Pr) complexes, the process of forma tion of (Na[Fe (CO)2C5H5]2)n, its structure changes and reaction regularities in the synthe ses of heteronuclear metal complexes were analyzed and discussed.

Key words: Polybis(cyclopentadienyldicarbonyliron)sodium, Reaction regularity, Heteronu clear metal complex

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