高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (4): 528.

• 论文 • 上一篇    下一篇

吲哚类新主体化合物的固相光化学合成及包结性能研究

孟继本, 杜大明, 王文广, 王永梅   

  1. 南开大学化学系, 天津, 300071
  • 收稿日期:1993-04-29 修回日期:1994-01-07 出版日期:1994-04-24 发布日期:1994-04-24
  • 通讯作者: 孟继本,男,55岁,教授,博士导师.
  • 作者简介:孟继本,男,55岁,教授,博士导师.
  • 基金资助:

    国家自然科学基金

Studies on Solid State Photochemical Syntheses and Inclusion Ability of New Host Compounds of Indoles

MENG Ji-Ben, DU Da-Ming, WANG Wen-Guang, WANG Yong-Mei   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1993-04-29 Revised:1994-01-07 Online:1994-04-24 Published:1994-04-24

PDF (PC)

被引次数

3

摘要： 对苯二甲醛、对甲酰基苯甲酸甲酯和邻硝基苯甲醛与吲哚的固相光反应得到5种新产物,其中4种产物具有很好的包结能力。产物1、2、3和4与丙酮、乙酸乙酯、四氯化碳、氯仿分别形成1:1、1:2或2:1包结络合物1a、2a、3a、4a和4b.并对包结络合物1a、2a和3a进行了X射线衍射结构解析。

关键词: 固相光化学, 包结能力, 包结络合物, 吲哚

Abstract: The photoreaction of terephthalicaldehyde, methyl p-formylbenzoate, and o-nitrobenzaldehyde with indole in the solid state gave five new products.Four of these products have a good inclusion ability.Products 1,2, 3 and 4 can form 1 : 1,1:2 or.2:1 inclusion complexes 1a, 2a, 3a, 4a and 4b with acetone, ethyl acetate, carbon tetrachloride, and chloroform respectively.The structures of products or inclusion complexes were identified by IR,1H NMR, MS and elemental analysis.X-ray diffraction analyses of inclusion complexes 1a,2a and 3a were carried out to obtain more information about the structures.

Key words: Solid state photochemistry, Inclusion ability, Inclusion complex, Indole

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