高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (12): 1830.

• 论文 • 上一篇    下一篇

乙酰丙酮稀土四苯基卟啉配合物的电化学研究

张恒彬, 孙树清, 刘国发, 李树家   

  1. 吉林大学化学系, 长春, 130023
  • 收稿日期:1994-01-27 修回日期:1994-08-16 出版日期:1994-12-24 发布日期:1994-12-24
  • 通讯作者: 张恒帐,男,52岁,教授.
  • 作者简介:张恒帐,男,52岁,教授.

Electrochemical Study on Acetylacetone-Tetraphenyl Porphyrin Rare Earth Complexes

ZHANG Heng-Bin, SUN Shu-Qing, LIU Guo-Fa, LI Shu-Jia   

  1. Department of Chemistry, Jilin University, Changchun, 130023
  • Received:1994-01-27 Revised:1994-08-16 Online:1994-12-24 Published:1994-12-24

摘要: 通过循环伏安测量研究了乙酰丙酮-5,10,15,20-四对氯苯基卟啉稀土配合物在二氯甲烷、水中的氧化还原性质,并同乙酰丙酮-5,10,15,20-四对甲氧基苯基卟啉稀土配合物的性质作了比较。

关键词: 稀土, 卟啉, 氧化还原, 循环伏安

Abstract: Redox properties of acetylacetone-tetra-(p-chlorophenyl) porphyrin rare earth complexes were characterized in dichloromethane or aqueous solution with cyclic voltammetry, and they were compared with those of acetylacetone-tetra-(p-methoxyphenyl) porphyrin rare earth complexes.

Key words: Rare earth, Porphyrin, Redox, Cyclic voltammetry

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