高等学校化学学报

高等学校化学学报 ›› 1994, Vol. 15 ›› Issue (11): 1623.

• 研究简报 • 上一篇    下一篇

脂溶性金属酞菁的合成及其作为PVC膜电极载体的研究

李俊忠, 庞新宇, 陆素, 高德, 俞汝勤   

  1. 湖南大学化学化工系, 长沙, 410082
  • 收稿日期:1993-12-18 修回日期:1994-04-21 出版日期:1994-11-24 发布日期:1994-11-24
  • 通讯作者: 俞汝勤.
  • 作者简介:李俊忠,男,27岁,博士研究生.
  • 基金资助:

    国家自然科学基金;中国科学院长春应用化学研究所电分析化学开放实验室资助

Synthesis of Lipophilic Metal Phthalocyanines and Application for Carriers of PVC Membrane Electrode

LI Jun-Zhong, PANG Xin-Yu, LU Shu, GAO De, YU Ru-Qin   

  1. Department of Chemistry and Chemieal Engineering, Hunan University, Changsha, 410082
  • Received:1993-12-18 Revised:1994-04-21 Online:1994-11-24 Published:1994-11-24

PDF (PC)

被引次数

3

关键词: 脂溶性金属酞菁, 载体, PVC膜电极

Abstract: Lipophilic 4, 4', 4", 4-tetra-tert-butylphthalocyanine cobalt(Ⅱ) and copper(Ⅱ)were synthesized using 4-tert-butylphthalic acid as the starting material.The followingproducts were ascertained through elemental analysis, IRand UV/Vis spectra.Thelipophilic compounds were used as carriers of PVCmembrane electrode, and it was foundthat the PVCmembrane electrode based on 4, 4', 4", 4-tetra-tert-butylphthalocyanine cobaltresponsed linearly to nitrite in a wide range with a high selectivety toward nitrite under theconditions.

Key words: Lipophilic metal phthalocyanines, Carriers, PVC membrane electrode

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