高等学校化学学报

高等学校化学学报 ›› 1993, Vol. 14 ›› Issue (8): 1055.

• 研究简报 • 上一篇    下一篇

铁(Ⅲ)卟啉轴向配位反应热力学研究

朱志昂, 阮文娟, 江冬青, 陈荣悌   

  1. 南开大学化学系, 天津 300071
  • 收稿日期:1992-08-04 修回日期:1992-11-30 出版日期:1993-08-24 发布日期:1993-08-24
  • 通讯作者: 朱志昂
  • 作者简介:第一作者:男, 54岁, 教授.
  • 基金资助:

    国家自然科学基金

Studies on the Thermodynamics of Axial Coordination Reaction of Porphinatoiron( Ⅲ )

ZHU Zhi-ANG, RUAN Wen-Juan, JIANG Dong-Qing, CHEN Rong-Ti   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1992-08-04 Revised:1992-11-30 Online:1993-08-24 Published:1993-08-24

PDF (PC)

被引次数

5

关键词: 氟合四-2, 4, 6-三甲苯基卟啉铁(Ⅲ), 轴向配位反应, 平衡常数, 核磁共振波谱

Abstract: Athermodynamic study is reported for the axial coordination of meso-tetrame-sitylporphinatoiron (Ⅲ) chloride (Fe(Ⅲ)TMPCl) with imidazole (Im), 2-methylimidazole (Melm), clotrimazole (CMZ ), 2-ethyl-4-methylimidazole (EMIm ) and 4'-imidazol-1-yl-ace-tophenone(ImAPh) in dichloromethane (这里有图片19930806-1055-1.gif) (1)The equilibrium constant (β) and stoichiometric number(n) of reaction (1) were measured by spectrophotometer technique.

Key words: Meso-tetramesitylporphinatoiron( Ⅲ ) chloride, Axial coordination reaction, Equilibrium constant, Nuclear magnetic resonance spectra

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