高等学校化学学报

高等学校化学学报 ›› 1992, Vol. 13 ›› Issue (10): 1251.

• 论文 • 上一篇    下一篇

键联双(口恶)唑类化合物的研究(Ⅱ)——4,4'-双[2"-(5"-取代苯基(口恶)唑基)]-1,1'-联苯及5,5'-双(二甲苯基)-2,2'-联(口恶)唑的结构与光性能研究

王明真, 张文勤, 高振衡   

  1. 南开大学化学系, 天津, 300071
  • 收稿日期:1991-11-09 修回日期:1992-04-21 出版日期:1992-10-24 发布日期:1992-10-24
  • 通讯作者: 王明真
  • 基金资助:

    国家自然科学基金

Research on Bond-Linked Bisoxazoles(Ⅱ)——Studies on the Structures and Optical Properties of 4,4'-bis[2"-(5"-Substituted Phenyl Oxazolyl)]-1,1'-Biphenyl and 5,5'-bis(Dimethylphenyl)-2,2'-Bioxazole

WANG Ming-Zhen, ZHANG Wen-Qin, GAO Zhen-Heng   

  1. Department of Chemistry, Nankai University, Tianjin, 300071
  • Received:1991-11-09 Revised:1992-04-21 Online:1992-10-24 Published:1992-10-24

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摘要： 本文合成了9种4.4'-双[2"(5"-_取代苯基(口恶)唑基)]-1,1'-联苯和3种5,5'-双(二甲苯基)-2,2'-联(口恶)唑,其中8种为未见报道的新化合物.讨论了上述化合物的结构与其电子光谱和激光性能间的关系,并总结出一些有一定意义的规律.

关键词: 结构, 激光转换效率, 空间效应

Abstract: Nine of 4,4'-bis[2"-(5"-substituted phenyl oxazolyl)]-1,1'-biphenyl and three of 5,5'-bis(dimethyl phenyl)-2,2'-bioxazole were synthesized.Eight of them are new compounds.The relationships between the structures of these compounds and their electron spectra,laser conversion efficiencies were discussed.Some valuable conclusions were summarized.

Key words: Structure, Laser conversion efficiency, Space effect

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