高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (10): 1284.

• 论文 • 上一篇    下一篇

稀土与杂环胺双齿配体配合物的研究(Ⅲ)--稀土三氯醋酸盐与2个α,α'-联吡啶的混配配合物的合成、性质及晶体结构

王君瑞1, 董南1, 吴光2, 郑培菊2   

  1. 1. 杭州大学化学系, 杭州, 310028;
    2. 复旦大学化学系
  • 收稿日期:1990-07-19 出版日期:1991-10-24 发布日期:1991-10-24
  • 通讯作者: 董南
  • 基金资助:

    国家自然科学基金

Studies on Complexes of the Rare Earth with the Bidentate Heterocyclic Amine Ligands(Ⅲ)--The Synthesis, Property and Crystal Structure of Complexes of Lanthanides Trichloroacetate with Two α,α'-Bipyridine

Wang Jun-rei1, Dong Nan1, Wu Guang2, Zheng Pei-ju2   

  1. 1. Department of Chemistry, Hamgzhou University, Hangzhou, 310028;
    2. Department of Chemistry, Fudan University
  • Received:1990-07-19 Online:1991-10-24 Published:1991-10-24

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摘要： 利用水和有机溶剂的混合溶剂合成了稀土三氯醋酸盐与2种α,α'-联吡啶的配合物,并进行了表征,还测定了Pr(TCA)3(bipy)2的晶体结构。

关键词: 稀土, 三氯醋酸盐, a, d-联吡啶, 高配比

Abstract: This paper presents the syntheses of the series complexes of lantnanides (except Pm) trichloroacetate with two α,α'-bipyridine from the mixed solvent of water and organic solvent, their properties were characterized, and the crystal structuer of Pr(TCA)3(bipy)2 was determined.

Key words: Rare earth, Trichloroacetate, a,a'-Bipyridine, High coordination ratio

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