高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (11): 1105.

• 研究论文 • 上一篇    下一篇

三苯基氧膦钕盐配合物的振动光谱

梁映秋1, 徐蔚青1, 黄春辉2   

  1. 1. 吉林大学理论化学研究所;
    2. 北京大学化学系
  • 收稿日期:1988-02-02 出版日期:1989-11-24 发布日期:1989-11-24
  • 通讯作者: 梁映秋
  • 基金资助:

    国家自然科学基金

Vibrational Spectra of Triphenylphosphine Oxide and Some Complexes

Liang Yingqiu1, Xu Weiqing1, Huang Chunhui2   

  1. 1. Institute of Theoretical Chemistry, Mm University, Changchun;
    2. Department of Chemistry, Peking University, Beijing
  • Received:1988-02-02 Online:1989-11-24 Published:1989-11-24

摘要: 本文测定了Ph3PO、Nd(NCS)3·4Ph3PO、[Nd(ClO4)2·4Ph3PO]+ClO4-·2CH3COCH3以及Nd(NO3)3·2Ph3PO·C2H5OH在4000~100cm-1区域内的FT-IR和激光Raman光谱,分析和讨论了各主要谱带的性质和配位结构.

关键词: IR光谱, 激光Raman光谱, 配合物

Abstract: FT-IRand Raman spectra(4000~100 cm-1) of PhsPO, Nd(NCS)3.4Ph3PO, [Nd(ClO4)2·4Ph3PO]+ClO4-·2CH3COCH3 and Nd (NO3)3·2Ph3PO·C2H5OHare measured.The properties of bands and the structure of complexes are analyzed and discussed.

Key words: Infra-red spectrum, Raman spectrum, Complex

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