高等学校化学学报

高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (1): 35.

• 研究论文 • 上一篇    下一篇

内-α-取代-α-甲基双环[2,2,1]庚烷-2-基甲醇的合成及其结构与香气的关系

汪小兰, 唐士雄, 游少春, 王长凤, 曹玉蓉   

  1. 南开大学化学系
  • 收稿日期:1987-07-07 出版日期:1989-01-24 发布日期:1989-01-24
  • 基金资助:

    中国科学院科学基金

Syntheses of Some Endo-o-Substituted-o-methyl Bicyclo[2,2,1]heptane-2-methanols and Relations Between Their Structures and Odors

Wang Xiaolan, Tang Shixiong, You Sbaocbun, Wang Cbangfeng, Cao Yurong   

  1. Department of Chemistry, Nankai University, Tianjin
  • Received:1987-07-07 Online:1989-01-24 Published:1989-01-24

PDF (PC)

摘要： 合成了18种内-α-取代-α-甲基双环[2,2,1]庚烷-2-基甲醇(Ⅰ)。测定了所有化合物的折光率(或熔点)、质谱、红外光谱、1H核磁共振谱、气相色谱的保留时间和薄层色谱的比移值。评定了它们的香气,并与相应的内-α-取代-α-甲基双环[2,2,1]-5-庚烯-2-基甲醇(Ⅱ)系列化合物的香气进行了比较,初步探讨了结构与香气的关系。

关键词: 内-&alpha, -取代-&alpha, -甲基双环[2, 2, 1]庚烷-2-基甲醇, 合成, 香气

Abstract: Eighteen title compounds were synthesized. The refractive indices (or melting points), retention times in GLC, Rf in TLC, MS, IR and 1HNMR spectra of these compounds were obtained. Their olfactory characteristics were evaluated and compared with endo-a-substituted-a-methylbicyclo[2, 2, 1]hept-5-ene-2-methanols. The relations between structures and odors were discussed.

Key words: Endo-a-Substituted-a-methylbicyclo[2,2,1]heptane-2-methanol, Synthesis, Odor

TrendMD: