高等学校化学学报 ›› 2026, Vol. 47 ›› Issue (6): 20260082.doi: 10.7503/cjcu20260082
• 综合评述 • 上一篇
魏颖真1, 冯婧怡2, 王若瑜1(
), 宋海涛1(
), 闫文付2(
)
收稿日期:2026-02-17
出版日期:2026-06-10
发布日期:2026-03-25
通讯作者:
王若瑜
E-mail:wangruoyu.ripp@sinopec.com;songht.ripp@sinopec.com;yanw@jlu.edu.cn
作者简介:宋海涛, 男, 博士, 研究员, 主要从事催化裂化催化剂及污染物转化助剂方面的研究. E⁃mail: songht.ripp@sinopec.com基金资助:
WEI Yingzhen1, FENG Jingyi2, WANG Ruoyu1(
), SONG Haitao1(
), YAN Wenfu2(
)
Received:2026-02-17
Online:2026-06-10
Published:2026-03-25
Contact:
WANG Ruoyu
E-mail:wangruoyu.ripp@sinopec.com;songht.ripp@sinopec.com;yanw@jlu.edu.cn
Supported by:摘要:
核壳结构复合催化剂具有不同功能组分非均匀分布的特征, 可通过空间分区对化学反应微环境进行精细调控, 因此在工业催化中具有广泛应用. 3D打印技术凭借结构可定制化的独特优势, 能够精准构筑具有多级孔道结构的自支撑催化剂; 其中同轴3D打印通过多通道墨水同步共挤出与可控沉积, 可一步实现多材料空间定向分布, 在核壳结构复合催化剂精确构筑与高效加工方面富有潜力. 本文综合评述了同轴3D打印核壳结构复合催化剂在设计制备及应用方面的研究进展, 系统阐述了同轴3D打印的工作原理、 同轴喷头的结构设计及3D打印墨水的配方体系; 还总结了3D打印核壳催化剂在机动车尾气净化、 液态有机污染物催化转化及挥发性有机化合物催化燃烧等领域的应用进展, 讨论了现阶段技术挑战及未来重点研究方向, 为新型核壳结构复合催化剂的工程化应用与高性能化开发提供了借鉴.
中图分类号:
TrendMD:
魏颖真, 冯婧怡, 王若瑜, 宋海涛, 闫文付. 同轴3D打印核壳结构复合催化剂研究进展. 高等学校化学学报, 2026, 47(6): 20260082.
WEI Yingzhen, FENG Jingyi, WANG Ruoyu, SONG Haitao, YAN Wenfu. Research Progress in Coaxial 3D Printed Core-shell Structured Composite Catalysts. Chem. J. Chinese Universities, 2026, 47(6): 20260082.
Fig.2 Schematic illustration of the fabrication for Cu⁃SSZ⁃13@SiO2 core⁃shell catalysts(A), digital photograph of Cu⁃SSZ⁃13@SiO2 catalyst with different 3D structures(B), SEM images of cross⁃sectional 3D⁃Cu⁃SSZ⁃13@SiO2⁃50 (C, D), SEM images of cross⁃sectional 3D⁃Cu⁃SSZ⁃13@SiO2⁃80(E, F), Scheme of the diffusion of reactant/product gas molecules over monolithic catalysts in NH3⁃SCR(G), NO conversion of 3D⁃Cu⁃SSZ⁃13, 3D⁃Cu⁃SSZ⁃13@SiO2⁃50, and 3D⁃Cu⁃SSZ⁃13@SiO2⁃80(H), Scheme of interaction between H2O molecules and catalysts during hydrothermal aging(I) and NO conversion of aged 3D⁃Cu⁃SSZ⁃13(3D⁃Cu⁃SSZ⁃13⁃A), aged 3D⁃Cu⁃SSZ⁃13@SiO2⁃50(3D⁃Cu⁃SSZ⁃13@SiO2⁃50⁃A), and 3D⁃Cu⁃SSZ⁃13@SiO2⁃80⁃A[19](J)Copyright 2023, Wiley-VCH.
Fig.3 Digital photograph of 3D⁃Pt/Al2O3 and 3D⁃Pt/Al2O3@Cu⁃SSZ⁃13(A), SEM images of cross⁃sectional 3D⁃Pt/Al2O3@Cu⁃SSZ⁃13 under different magnifications(B—D) and NH3 conversion and N2 yield over 3D⁃Pt/Al2O3 and 3D⁃Pt/Al2O3@Cu⁃SSZ⁃13(E)[19]Copyright 2023, Wiley-VCH.
Fig.4 NO x profiles(A) and amount of NO x of 3D⁃printed Pd/CHA and Mn/CHA@Pd/CHA monoliths(B), cyclic NO x profiles of 3D⁃printed Mn/CHA@Pd/CHA monolith(C) and schematic illustration of the NO x adsorption(left) and desorption(right) mechanism for 3D⁃printed Mn/CHA@Pd/CHA monoliths: the Mn/CHA core is encircled by the Pd/CHA shell(D)[55]Copyright 2024, Wiley-VCH.
Fig.5 Schematic diagrams(A), cross⁃sectional SEM images(B) and cold start transient test runs with 5% H2O of core⁃shell monolith, dual⁃layer monolith, and physically mixed monolith(C)[59]Copyright 2026, Elsevier Ltd..
Fig.6 Schematic of Me/CFBR preparation based on coaxial biostructure of bamboo(A), SEM images of the cross⁃section of the CFBR(B, C) and conversion rate of 4⁃NP obtained using reduced Me/CFBR(D)[58]Copyright 2026, Elsevier Ltd..
Fig.7 Schematic diagram of the preparation process for coaxial 3D printed Pd/C catalytic reactor(A), cross⁃sectional images of Pd/C catalytic reactor with nuclear diameters of 3.8, 2.8, 1.8 mm(B—D), 3D printing coaxial Pd/C catalytic reactor with the special shapes of U⁃type, W⁃type, and L⁃type (E—G) and plot of conversion vs. time for Pd/C catalytic reactor with different types(H)[56]Copyright 2026, Elsevier Ltd..
Fig.8 Schematic diagram of the preparation and application for 3D printed CM/Z5@Z5 core⁃shell catalyst[57]Copyright 2024, Editorial office of Chem. J. Chinese Universities.
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