Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (8): 1455.doi: 10.7503/cjcu20150259
• Articles: Inorganic Chemistry • Previous Articles Next Articles
ZHAO Lun1,2, ZHANG Min1,2, DENG Qinghui2, WANG Zichen1,*()
Received:
2015-04-01
Online:
2015-08-10
Published:
2015-07-17
Contact:
WANG Zichen
E-mail:wangzc@jlu.edu.cn
TrendMD:
ZHAO Lun, ZHANG Min, DENG Qinghui, WANG Zichen. Synthesis and Characterization of Two Novel Cu(Ⅱ) Coordination Polymers with Helical Crystal Structure†[J]. Chem. J. Chinese Universities, 2015, 36(8): 1455.
Compd. | 1 | 2 |
---|---|---|
CCDC No. | 1047034 | 1047035 |
Formula | C50H34Cu2N4O9 | C32H27CuN3O6 |
Formula weight | 961.89 | 613.11 |
Crystal system | Orthorhombic | Monoclinic |
Space group | Pnma | P21/c |
a/nm | 1.15377(10) | 1.2656(2) |
b/nm | 2.3293(2) | 0.92408(15) |
c/nm | 1.62888(14) | 2.5544(4) |
α/(°) | 90.00 | 90.00 |
β/(°) | 90.00 | 96.158(4) |
γ/(°) | 90.00 | 90.00 |
V/nm3 | 4.3776(7) | 6.4595(7) |
Z | 4 | 4 |
Dc/(g·cm-3) | 1.459 | 1.371 |
F(000) | 1968.0 | 1268 |
GOF on F2 | 1.052 | 0.976 |
R1/wR2[I>2σ(I)] | 0.0565/0.1369 | 0.0719/0.1972 |
R1/wR2(All data) | 0.1084/0.1738 | 0.1462/0.2358 |
Table 1 Crystal data and structure refinement of compounds 1 and 2
Compd. | 1 | 2 |
---|---|---|
CCDC No. | 1047034 | 1047035 |
Formula | C50H34Cu2N4O9 | C32H27CuN3O6 |
Formula weight | 961.89 | 613.11 |
Crystal system | Orthorhombic | Monoclinic |
Space group | Pnma | P21/c |
a/nm | 1.15377(10) | 1.2656(2) |
b/nm | 2.3293(2) | 0.92408(15) |
c/nm | 1.62888(14) | 2.5544(4) |
α/(°) | 90.00 | 90.00 |
β/(°) | 90.00 | 96.158(4) |
γ/(°) | 90.00 | 90.00 |
V/nm3 | 4.3776(7) | 6.4595(7) |
Z | 4 | 4 |
Dc/(g·cm-3) | 1.459 | 1.371 |
F(000) | 1968.0 | 1268 |
GOF on F2 | 1.052 | 0.976 |
R1/wR2[I>2σ(I)] | 0.0565/0.1369 | 0.0719/0.1972 |
R1/wR2(All data) | 0.1084/0.1738 | 0.1462/0.2358 |
Fig.1 Crystal structures of compound 1(A) Coordination environment of the Cu(Ⅱ) ions in compound 1, the hydrogen atoms are omitted for clarity; (B) 2D net structure; (C) the helical chains in the (4,4) layers; (D) the helical chains.
Fig.2 Crystal structures of compound 2(A) Coordination environment of the Cu(Ⅱ) ions in compound 2, the hydrogen atoms are omitted for clarity; (B) 2D net structure;(C) the 3D framework; (D) the { 44·610·8} topology net; (E) the helical chains in the (4,4) layers; (F) the helical chains.
[1] | Furukawa H., Cordova K. E., O’Keeffe M., Yaghi O. M., Science, 2013, 341(6149), 1230441 |
[2] | Leus K., Liu Y. Y., van der Voort P., Catal. Rev. Sci. Eng., 2014, 56(1), 1—56 |
[3] | Wang C. C., Li J. R., Lv X. L., Zhang Y. Q., Guo G., Energy Environ. Sci., 2014, 7(9), 2831—2867 |
[4] | Lei J., Qian R., Ling P., Cui L., Ju H., Trac-Trend. Anal. Chem., 2014, 58, 71—78 |
[5] | Cai K., Zhang L. N., Han L. Q., Qu F. Y., Chem. J. Chinese Universities, 2013, 34(6), 1313—1317 |
(蔡锟, 张玲娜, 韩丽琴, 曲凤玉. 高等学校化学学报, 2013, 34(6), 1313—1317) | |
[6] | Piromchom J., Wannarit N., Boonmak J., Chainok K., Pakawatchai C., Youngme S., Inorg. Chem. Commun., 2014, 44, 111—113 |
[7] | Eddaoudi M., Kim J., Rosi N., Vodak D., Wachter J., O'Keeffe M., Yaghi O. M., Science, 2002, 295(5554), 469—472 |
[8] | He Y., Zhou W., Qian G., Chen B., Chem. Soc. Rev., 2014, 43(16), 5657—5678 |
[9] | Herm Z. R., Bloch E. D., Long J. R., Chem. Mater., 2014, 26(1), 323—338 |
[10] | Duan C. J., Cao Y. M., Jie X. M., Wang L. N., Yuan Q., Chem. J. Chinese Universities, 2014, 35(7), 1584—1589 |
(段翠佳, 曹义鸣, 介兴明, 王丽娜, 袁权. 高等学校化学学报, 2014, 35(7), 1584—1589) | |
[11] | Kreno L. E., Leong K., Farha O. K., Allendorf M., van Duyne R. P., Hupp J. T., Chem. Rev., 2012, 112(2), 1105—1125 |
[12] | Zha Q., Rui X., Wei T., Xie Y., CrystEngComm, 2014, 16(32), 7371—7384 |
[13] | Zhou J., Wang Y., Qin L., Zhang M., Yang Q., Zheng H., CrystEngComm, 2013, 15(3), 616—627 |
[14] | Zha Q., Ding C., Rui X., Xie Y., Cryst. Growth Des., 2013, 13(10), 4583—4590 |
[15] | Wang X., Gong C., Qu Y., Liu G., Zhang J., Chem. Res. Chinese Universities, 2014, 30(5), 709—714 |
[16] | Lesniewska B., Perret F., Suwinska K., Coleman A. W., CrystEngComm, 2014, 16(21), 4399—4405 |
[17] | Ma B. H., Peng Y., Hua J., Shi Zhan., Chem. J. Chinese Universities, 2015, 36(2), 215—220 |
(马本华, 彭宇, 华佳, 施展. 高等学校化学学报, 2015, 36(2), 215—220) | |
[18] | Xu B., Liang Q. S., Liu L. T., Liu Q. S., Li C. C., RSC Adv., 2014, 4(27), 13919—13926 |
[19] | Ding C., Li X., Ding Y., Li X., Ng S. W., Xie Y., Cryst. Growth Des., 2012, 12(7), 3465—3473 |
[20] | Gu J., Jiang X., Su Z., Zhao Z., Zhou B., Inorg. Chim. Acta, 2013, 400, 210—214 |
[21] | Fukuhara K., Noro S., Sugimoto K., Akutagawa T., Kubo K., Nakamura T., Inorg. Chem., 2013, 52(8), 4229—4237 |
[22] | Xu B., Sun Y. Q., Li J., Li C. C., RSC Adv., 2014, 4(49), 25588—25595 |
[23] | Yuan S., Liu S. S., Sun D., CrystEngComm, 2014, 16(10), 1927—1933 |
[24] | Bhattacharya S., Goswami A., Gole B., Ganguly S., Bala S., Sengupta S., Khanra S., Cryst. Growth Des., 2014, 14(6), 2853—2865 |
[25] | Li L. J., Wang X. L., Shao K. Z., Su Z. M., Fu Q., Inorg. Chim. Acta, 2012, 392, 77—83 |
[26] | Yang J. X., Qin Y. Y., Cheng J. K., Yao Y. G., Cryst. Growth Des., 2014, 14(3), 1047—1056 |
[27] | Wang H., Yang X. Y., Ma Y. Q., Cui W. B., Li Y. H., Tian W. G., Yao S., Gao Y., Dang S., Zhu W., Inorg. Chim. Acta, 2014, 416, 63—68 |
[28] | Hu J. S., Zhuo X., Liu X. H., Xing H. L., He J., Zheng H. G., Inorg. Chem. Commun., 2013, 33, 15—18 |
[29] | Beheshti A., Lalegani A., Bruno G., Rudbari H. A., J. Mol. Struct., 2014, 1071, 18—22 |
[30] | Ding C., Rui X., Wang C., Xie Y., CrystEngComm, 2014, 16(6), 1010—1019 |
[31] | Nobakht V., Beheshti A., Proserpio D. M., Carlucci L., Abrahams C. T., Inorg. Chim. Acta, 2014, 414, 217—225 |
[32] | Zhou J. L., Wang Y. Y., Zhou M. J., Qin L., Zhang M. D., Yang Q. X., Zheng H. G., Inorg. Chem. Commun., 2014, 40, 148—150 |
[33] | Liu B., Zhang Q., Ding H., Hu G., Du Y., Wang C., Wu J., Li S., Zhou H., Yang J., Tian Y., Dyes Pigm., 2012, 95(1), 149—160 |
[34] | Liou S. G., Hsiao S. H., Su T. H., J. Mater. Chem., 2005, 15, 1812—1820 |
[35] | Sheldrick G. M., Acta Crystallogr. Sect. C: Cryst. Struc. Chem., 2015, 71, 3—8 |
[36] | Sheldrick G. M., Acta Crystallogr. Sect. A, 2008, 64, 112—122 |
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