A Multi-functional Zn（II） Coordination Polymer with Luminescence Sensing， Amperometric Sensing， and Dye Adsorption Performance

doi:10.7503/cjcu20210585

Abstract

Abstract:

A porous coordination polymer Zn（4-bpft）（1，4-bdc）］（CP 1） was constructed from the N，N′-bis（4-pyridine formamide）-3，4-thiophene（4-bpft） and terephthalic acid （1，4-H₂bdc） mixed-ligand under hydrothermal condition. It’s structure and composition were characterized by means of single crystal X-ray diffraction， FTIR and PXRD techniques. The results show that CP 1 is a 2D network with 17.3% of solvent accessible void space by PLATON， which exhibits a 3-connected network with ｛6³｝ topology. CP 1 displays obvious fluorescent turning on sensing and can efficiently detect asparticacid（Asp）. It also exhibits electrochemically reversible redox behavior， and can be used as an amperometric sensor for detecting ascorbic acid（AA）. In addition， the adsorption behavior of CP 1 was evaluated with organic dyes methylene blue（MB）， gentian purple（GV）， and neutral red（NR）， implying it has potential application value in removing organic pollutants.

Key words: Coordination polymer, Fluorescence sensing, Electrochemical behavior, Dye adsorption property

CLC Number:

O614

TrendMD:

MA Jianxin, LIU Xiaodong, XU Na, LIU Guocheng, WANG Xiuli. A Multi-functional Zn（II） Coordination Polymer with Luminescence Sensing， Amperometric Sensing， and Dye Adsorption Performance[J]. Chem. J. Chinese Universities, 2022, 43(1): 20210585.

Figures/Tables 4

Fig. 1 Coordination environment of Zn2+ in CP 1(A) and [Zn2(4?bpft)2] loop and 1D chain along a axis(B), 2D network(C) and 2D {63} topology(D) of CP 1

Fig.2 Luminescence intensities of CP 1 scattered in amino acid solutions(A), changes in the luminescence spectra of CP 1 with different amounts of Asp(B), relationship between(I0-I)/I0 and the concentration of Asp(C), luminescence intensities for CP 1 without and with the addition of eight amino acids and Asp(D)

Fig.3 CV response of 1?CPE at different scan rates(A), CVs of 1?CPE in testing solution containing different concentrations of AA(B), current response after continuously adding AA to 1?CPE(inset: the relationship between current and concentration of AA)(C) and stability of CP 1 to AA for working 25000 s(D)

Fig.4 UV?Vis spectra at different time in the adsorption experiments and the corresponding adsorption pictures of MB(A), GV(B) and NR(C)

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