Chiral Metal-organic Frameworks [Mn3(HCOO)4(D-Cam)]n Used for Gas Chromatographic Separation

Abstract

Abstract:

Chiral metal-organic frameworks(MOFs) have recently received great attention in enantioselective catalysis and chiral separation areas because of their unusual properties such as high surface areas, diverse topologies and excellent chemical and thermal stability. A three-dimensional chiral MOF [Mn₃(HCOO)₄·(D-Cam)] _n with homochiral chain was used as stationary phase for column A(30 m×250 μm i.d.) and column B(5 m×75 μm i.d.) in gas chromatography. We investigated the coating properties of stationary phase by scanning electron microscope(SEM) on capillary column inner wall and the thermal stability by thermogravimetric analysis(TGA). Some racemates, alkanes and isomers were used as targets for separation on column B. The experimental results showed that the stationary phase also possessed good separation ability toward these organic compounds.

Key words: Metal-organic framework, Racemate, Stationary phase, Capillary column, Gas chromatography

CLC Number:

O657.7

TrendMD:

XIE Shengming, ZHANG Zejun, YUAN Liming. Chiral Metal-organic Frameworks [Mn₃(HCOO)₄(D-Cam)]_n Used for Gas Chromatographic Separation[J]. Chem. J. Chinese Universities, 2014, 35(8): 1652.

References

[1] Wei W. Y., Fang J., Kong H. N., Han J. Y., Chang H. Y., Progress in Chemistry, 2005, 17(6), 1110-1114(魏文英, 方键, 孔海宁, 韩金玉, 常贺英. 化学进展, 2005, 17(6), 1110-1114)

[2] Mu C. Z., Xu F., Lei W., Progress in Chemistry, 2007, 19(9), 1345-1356(穆翠枝, 徐峰, 雷威. 化学进展, 2007, 19(9), 1345-1356)

[3] Furukawa H., Michael M. A., Yaghi O. M., J. Mater. Chem., 2007, 17(30), 3197-3204

[4] Ma S. Q., Sun D. F., Simmons J. M., Collier C. D., Yuan D. Q., Zhou H. C., J. Am. Chem. Soc., 2008, 130(3), 1012-1016

[5] Horcajada P., Serre C., Vallet-Regi M., Sebban M., Taulelle F., Ferey G., Angew. Chem. Int. Ed., 2006, 45(36), 5974-5978

[6] Yang B. C., Jiang Y. D., Qin X. J., Chen Z. L., Ren F., Chem. J. Chinese Universities, 2012, 33(1), 26-31(杨宝春, 姜耀东, 秦雪娟, 陈志良, 任非. 高等学校化学学报, 2012, 33(1), 26-31)

[7] Li Z. Q., Wang A., Guo C. Y., Hu W. N., Tai Y. F., Chem. J. Chinese Universities, 2013, 34(11), 2470-2477(李宗群, 汪艾, 郭春燕, 胡文娜, 邰燕芳. 高等学校化学学报, 2013, 34(11), 2470-2477)

[8] Chen B., Liang C., Yang J., Contreras D. S., Clancy Y. L., Lobkovsky E. B., Yaghi O. M., Dai S., Angew. Chem. Int. Ed., 2006, 45(9), 1390-1393

[9] Couck S., Denayer J. F. M., Baron G. V., Remy T., Gascon J., Kapteijn F., J. Am. Chem. Soc., 2009, 131(18), 6326-6327

[10] Gu Z. Y., Yan X. P., Angew. Chem. Int. Ed., 2010, 49(8), 1477-1480

[11] Chang N., Gu Z. Y., Yan X. P., J. Am. Chem. Soc., 2010, 132(39), 13645-13647

[12] Gu Z. Y., Jiang D. Q., Wang H. F., Cui X. Y., Yan X. P., J. Phys. Chem. C, 2010, 114(1), 311-316

[13] Yang C. X., Yan X. P., Anal. Chem., 2011, 83(18), 7144-7150

[14] Gu Z. Y., Jiang J. Q., Yan X. P., Anal. Chem., 2011, 83(13), 5093-5100

[15] Yang C. X., Chen Y. J., Wang H. F., Yan X. P., Chem. Eur. J., 2011, 17(42), 11734-11737

[16] Gu Z. Y., Yang C. X., Chang N., Yan X. P., Acc. Chem. Res., 2012, 45(5), 734-745

[17] Fu Y. Y., Yang C. X., Yan X. P., Langmuir, 2012, 28(17), 6794-6802

[18] Liu S. S., Yang C. X., Wang S. W., Yan X. P., Analyst, 2012, 137(4), 816-818

[19] Chang N., Yan X. P., J. Chromatogr. A, 2012, 1257, 116-124

[20] Fan L., Yan X. P., Talanta, 2012, 99, 944-950

[21] Yang C. X., Liu S. S., Wang H. F., Wang S. W., Yan X. P., Analyst, 2012, 137(1), 133-139

[22] Fu Y. Y., Yang C. X., Yan X. P., J. Chromatogr. A, 2013, 1274, 137-144

[23] Wu C. D., Lin W. B., Angew. Chem. Int. Ed., 2007, 46(7), 1075-1078

[24] Gandara F., Gornez-Lor B., Gutierrez-Puebla E., Iglesias M., Monge M. A., Proserpio D. M., Snejko N., Chem. Mater., 2008, 20(1), 72-76

[25] Horike S., Dinc? M., Tamaki K., Long J. R., J. Am. Chem. Soc., 2008, 130(18), 5854-5855

[26] Aijaz A., Akita T., Tsumori N., Xu Q., J. Am. Chem. Soc., 2013, 135(44), 16356-16359

[27] Chandler B. D., Cramb D. T., Shimizu G. K. H., J. Am. Chem. Soc., 2006, 128(32), 10403-10412

[28] Bauer C. A., Timofeeva T. V., Settersten T. B., Patterson B. D., Liu V. H., Simmons B. A., Allendorf M. D., J. Am. Chem. Soc., 2007, 129(22), 7136-7144

[29] Li Y. X., Xue M., Guo L. J., Huang L., Chen S. R., Qiu S. L., Chem. Res. Chinese Universities, 2013, 29(2), 196-200

[30] Li Y. X., Xue M., Huang L., Chen S. R., Qiu S. L., Chem. Res. Chinese Universities, 2013, 29(4), 611-616

[31] Chen B. L., Yang Y., Zapata F., Lin G. N., Qian G. D., Lobkovsky E. B., Adv. Mater., 2007, 19(13), 1693-1696

[32] Chen B. L., Wang L. B., Zapata F., Qian G. D., Lobkovsky E. B., J. Am. Chem. Soc., 2008, 130(21), 6718-6719

[33] Allendorf M. D., Houk R. J. T., Andruszkiewicz L., Talin A. A., Pikarsky J., Choudhury A., Gall K. A., Hesketh P. J., J. Am. Chem. Soc., 2008, 130(44), 14404-14405

[34] Yang C. X., Yan X. P., Chin. J. Anal. Chem., 2013, 41(9), 1297-1301(杨成雄, 严秀平. 分析化学, 2013, 41(9), 1297-1301)

[35] Kesanli B., Lin W. B., Coord. Chem. Rev., 2003, 246(1/2), 305-326

[36] Dybtsev D. N., Nuzhdin A. L., Chun H., Bryliakov K. P., Talsi E. P., Fedin V. P., Kim K., Angew. Chem. Int. Ed., 2006, 45(6), 916-920

[37] Li G., Yu W., Ni J., Liu T., Liu Y., Sheng E., Cui Y., Angew. Chem. Int. Ed., 2008, 47(7), 1245-1249

[38] Li G., Yu W., Cui Y., J. Am. Chem. Soc., 2008, 130(14), 4582-4583

[39] Ma L. Q., Abney C., Lin W. B., Chem. Soc. Rev., 2009, 38(5), 1248-1256

[40] Zhang M., Pu Z. J., Chen X. L., Gong X. L., Zhu A. X., Yuan L. M., Chem. Commun., 2013, 49(45), 5201-5203

[41] Zhang M., Zhang J. H., Zhang Y., Wang B. J., Xie S. M., Yuan L. M., J. Chromatogr. A, 2014, 1325, 163-170

[42] Zhang M., Xue X. D., Zhang J. H., Xie S. M., Zhang Y., Yuan L. M., Anal. Methods, 2014, 6(2), 341-346

[43] Xie S. M., Zhang Z. J., Wang Z. Y., Yuan L. M., J. Am. Chem. Soc., 2011, 133(31), 11892-11895

[44] Xie S. M., Zhang X. H., Zhang Z. J., Yuan L. M., Anal. Lett., 2013, 46(5), 753-763

[45] Xie S. M., Zhang X. H., Zhang Z. J., Zhang M., Jia J., Yuan L. M., Anal. Bioanal. Chem., 2013, 405(10), 3407-3412

[46] Zhang X. H., Xie S. M., Duan A. H., Wang B. J., Yuan L. M., Chromatographia, 2013, 76(13/14), 831-836

[47] Xie S. M., Wang B. J., Zhang X. H., Zhang J. H., Zhang M., Yuan L. M., Chirality, 2014, 26(1), 27-32

[48] Xue X. D., Zhang M., Xie S. M., Yuan L. M., Acta Chromatographica, 2013, doi:10.1556/AChrom.27.2015.1.2

[49] Zhang J., Chen S. M., Valle H., Wong M., Austria C., Cruz M., Bu X. H., J. Am. Chem. Soc., 2007, 129(46), 14168-14169

Chiral Metal-organic Frameworks [Mn₃(HCOO)₄(D-Cam)]_n Used for Gas Chromatographic Separation

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHAO Yingzhe, ZHANG Jianling. Applications of Metal-organic Framework-based Material in Carbon Dioxide Photocatalytic Conversion [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220223.
[2]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[3]	JI Shuangqi, JIN Zhao, GUAN Wenna, PAN Xiangyu, GUAN Tong. Preparation and Chromatographic Performance of Mixed-mode Silica Stationary Phase Modified by Double Cationic Ionic Liquid and Octadecyl Group [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220008.
[4]	TIAN Xueqin, MO Zheng, DING Xin, WU Pengyan, WANG Yu, WANG Jian. A Squaramide-containing Luminescent Metal-organic Framework as a High Selective Sensor for Histidine [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210589.
[5]	QIN Gaizhao, TANG Minghua, LAI Yalin, YUAN Liming. Chiral Metal-organic Cage MOC-PA as a Chiral Stationary Phase for Capillary Electrophoresis [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220417.
[6]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.
[7]	MO Zongwen, ZHANG Xuewen, ZHOU Haolong, ZHOU Dongdong, ZHANG Jiepeng. Guest-responses of A Porous Coordination Polymer Based on Synergistic Hydrogen Bonds [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210576.
[8]	LIU Xueguang, YANG Xiaoshan, MA Jingjing, LIU Weisheng. Separating Methyl Blue Selectively from the Mixture of Dyes by Europium Metal-organic Frameworks [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210715.
[9]	SHI Xiaofan, ZHU Jian, BAI Tianyu, FU Zixuan, ZHANG Jijie, BU Xianhe. Research Status and Progress of MOFs with Application in Photoelectrochemical Water-splitting [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210613.
[10]	WU Ji, ZHANG Hao, LUO Yuhui, GENG Wuyue, LAN Yaqian. A Microporous Cationic Ga（III）-MOF with Fluorescence Properties for Selective sensing Fe³⁺ Ion and Nitroaromatic Compounds [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210617.
[11]	LI Wen, QIAO Junyi, LIU Xinyao, LIU Yunling. Zirconium-based Metal-Organic Framework with Naphthalene for Fluorescent Detection of Nitroaromatic Explosives in Water [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210654.
[12]	WANG Jie, HUO Haiyan, WANG Yang, ZHANG Zhong, LIU Shuxia. General Strategy for In situ Synthesis of NENU-n Series Polyoxometalate-based MOFs on Copper Foil [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210557.
[13]	HAN Zongsu, YU Xiaoyong, MIN Hui, SHI Wei, CHENG Peng. A Rare Earth Metal-Organic Framework with H₆TTAB Ligand [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210342.
[14]	LI Shurong, WANG Lin, CHEN Yuzhen, JIANG Hailong. Research Progress of Metal⁃organic Frameworks on Liquid Phase Catalytic Chemical Hydrogen Production [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210575.
[15]	ZHANG Chi, SUN Fuxing, ZHU Guangshan. Synthesis， N₂ Adsorption and Mixed-matrix Membrane Performance of Bimetal Isostructural CAU-21 [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210578.