Guest-responses of A Porous Coordination Polymer Based on Synergistic Hydrogen Bonds

doi:10.7503/cjcu20210576

Abstract

Abstract:

Solvothermal reaction of Zn（NO₃）₂·6H₂O， pyrazole-3， 5-dicarboxylic acid （H₃pzdc） and 2-amino-1，4-benzenedicarboxylic acid （H₂abdc） in N，N-dimethylformamide（DMF） produced a porous coordination polymer（Me₂NH₂）［Zn₂（pzdc）（abdc）］·H₂O·DMF（1·g， g means guest molecules， H₂O and DMF）， in which Me₂NH₂⁺ was generated from the hydrolysis of the solvent DMF. The 3-dimensional porous coordination framework of 1 can be regarded as a pillared-ribbon structure consisting of parallelly-aligned flat ｛Zn₂（pzdc）｝⁺ ribbons and abdc^2- pillars. via desorption/adsorption of solvent molecules， centrosymmetric 1·g can reversibly transform to a chiral framework （Me₂NH₂）［Zn₂（pzdc）（abdc）］（1'）. Single-crystal X-ray diffraction analyses showed that， based on the competition and cooperation of hydrogen bonds among the host framework， counter cations， and neutral guest molecules， the counter cations underwent significant movement and rotation in the guest-responsive structural transformations， giving rise to the distortion and rotation of the ｛Zn₂（pzdc）｝⁺ ribbon， as well as more than 10% changes of the unit-cell volume and void ratio. Gas adsorption measurements of 1' showed different responses toward N₂ and CO₂.

Key words: Metal-organic framework, Flexibility, Guest response, Counter ion

CLC Number:

O614.24

TrendMD:

MO Zongwen, ZHANG Xuewen, ZHOU Haolong, ZHOU Dongdong, ZHANG Jiepeng. Guest-responses of A Porous Coordination Polymer Based on Synergistic Hydrogen Bonds[J]. Chem. J. Chinese Universities, 2022, 43(1): 20210576.

Figures/Tables 3

References 22

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