Synthesis and Characterization of the Heterobinuclear Transition Metal Complexes of the Schiff Base Derived from 3-Formylsalicylic Acid and Trimethylenediamine

Chem. J. Chinese Universities ›› 1991, Vol. 12 ›› Issue (5): 587.

• Articles • Previous Articles Next Articles

Synthesis and Characterization of the Heterobinuclear Transition Metal Complexes of the Schiff Base Derived from 3-Formylsalicylic Acid and Trimethylenediamine

Zhou Xu-ya, Tao Ruo-jie, Yu Zhao-wen, Jin Dou-man

1. Dept. of Chemistry, Hewn University, Kaifeng, 475001;
2. Henan Institute of Chemistry, Zhengzhou

Received:1990-01-12 Online:1991-05-24 Published:1991-05-24

Abstract

Abstract: Copper (Ⅱ)-M(Ⅱ) heterobinuclear complexes of the schiff base derived from 3-formylsali-cylic acid and trimethylenediamine, CuMTS · 2H₂O(M = Zn,Co,Fe,Mn, Mg), were synthesized. AHthese compounds were characterized by elemental analysis, IR, UV-visible spectra and room tem-preture magnetic moments. In DMSO, the electrochemical properties of this species were examined by cyclic voltammetry, differential pulse polarography and DCpolarography. The relationship between properties and structures was studied.

Key words: 3-formylsalicylic acid, Schiff base, Heterobinuclear complexes, Cyclic voltammetry, Differential pulse polarography

TrendMD:

Zhou Xu-ya, Tao Ruo-jie, Yu Zhao-wen, Jin Dou-man. Synthesis and Characterization of the Heterobinuclear Transition Metal Complexes of the Schiff Base Derived from 3-Formylsalicylic Acid and Trimethylenediamine[J]. Chem. J. Chinese Universities, 1991, 12(5): 587.

[1]	XU Dandan, ZOU Xiucheng, LUO Jing, LIU Ren. Synthesis and Characterization of Phenothiazine-based Schiff Bases as Visible Light Photoinitiators [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210857.
[2]	CAO Cheng,CAO Tian,YAN Penji,WANG Qingyun,YUE Guoren,JI Xiangdong. High Selectivity of Enol-keto Tautomers Imine Derivative for the Recognition of Co²⁺^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1544.
[3]	CAI Yanchao,NIU Pengfei,SHEN Zhenlu,LI Meichao. Electrocatalytic Oxidative Coupling of Primary Amines with the Medium ABNO ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2308.
[4]	ZHANG Jiayi,JIA Mengyang,JIANG Xiaohui,ZHANG Zhiming,YU Liangmin,WANG Xuan. Antifouling Properties of Dodecyl Benzene Sulfonic Acid Doped Polypyrrole Under Alternating Anodic-cathodic Polarization ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2396.
[5]	SUN Jie, MING Tingyun, QIAN Huixuan, ZHANG Manke, TAN Yong. Electrochemical Behavior of Copper Electrodeposition in BMIMPF₆ Ionic Liquid [J]. Chem. J. Chinese Universities, 2018, 39(7): 1497.
[6]	ZHAO Bangtun, TAO Jingjing, CHEN Xiaoji, FU Huimin, ZHU Weimin. Synthesis, Structure and Electrochemistry of Tetrathiafulvalene Vinylogues Bearing Thienyl and Pyridyl Groups^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1449.
[7]	ZHAO Changjiang,LIU Xin,TIAN Li,ZHAO Lun. Synthesis, Structure and Electrochemical Properties of Metal Cobalt Complexes with Interpenetrating Structures^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 861.
[8]	ZHAO Bangtun, MA Shuxiu, TAO Jingjing, ZHU Weimin. Synthesis, Structures and Electrochemical Properties of Pyridine-based Tetrathiafulvalene Derivatives^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 193.
[9]	GAO Lijuan, WANG Li, WANG Shengyan, JING Shubo. Influence of Solvent on Structure of Ni(Ⅱ) Metal-organic Frameworks^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1589.
[10]	ZHANG Xuena, ZHONG Xinwen, ZHONG Yan, LU Haiyan. Optimization of Conditions of the Electrochemical Detection of Methamphetamine^† [J]. Chem. J. Chinese Universities, 2016, 37(10): 1799.
[11]	XIONG Xingquan, JIANG Yunbing, XIAO Shangyun, SHI Lin, SONG Sida. Highly Efficient Synthesis of 1,2,3-Triazoles Catalyzed by Schiff Base Functionalized Chitosan-CuBr Catalyst^† [J]. Chem. J. Chinese Universities, 2016, 37(10): 1863.
[12]	LÜ Jiangwei, QU Youpeng, FENG Yujie, LIU Junfeng. Electrochemical Impedance Spectroscopy of Dichlorophenols at Boron-doped Diamond Electrodes^† [J]. Chem. J. Chinese Universities, 2016, 37(1): 142.
[13]	WU Ranran, TIAN Xiaochun, WU Shenjian, LIU Yuangang, JIANG Yanxia, ZHAO Feng. Research on the Electrochemical Activity of Magnetospirillum Magneticum AMB-1^† [J]. Chem. J. Chinese Universities, 2015, 36(9): 1730.
[14]	WANG Zijian, SUN Xiaohong, LIU Yuanfa, CHEN Bang, SHEN Shengqiang, JIN Ruyi, MA Haixia. Synthesis and Biological Activities of 1,2,4-Triazole Schiff Bases Containing Pyrazole Rings^† [J]. Chem. J. Chinese Universities, 2015, 36(7): 1315.
[15]	HUANG Jian, LIU Zhigang, FAN Ruiqing, DONG Yuwei, ZHANG Huijie, WANG Yulei, YANG Yulin. Synthesis, Characterization and Blue-emission of Cd(Ⅱ)Coordination Polymers with μ-Chlorine-Bridging One-dimensional Chain Structures^† [J]. Chem. J. Chinese Universities, 2015, 36(3): 411.

Synthesis and Characterization of the Heterobinuclear Transition Metal Complexes of the Schiff Base Derived from 3-Formylsalicylic Acid and Trimethylenediamine

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments