Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (3): 448.doi: 10.7503/cjcu20180521
• Analytical Chemistry • Previous Articles Next Articles
LI Ying*(), KANG Junjun, ZHAO Xueru, XU Wenkai, QI Qi
Received:
2019-07-24
Online:
2019-03-10
Published:
2019-08-21
Contact:
LI Ying
E-mail:liying_791190@163.com
Supported by:
CLC Number:
TrendMD:
LI Ying, KANG Junjun, ZHAO Xueru, XU Wenkai, QI Qi. Preparation of Gold-modified Magnetic Graphene-based Molecularly Imprinted Composites and Electrochemical Sensing Detection of Dinbutyl Phthalate in Water†[J]. Chem. J. Chinese Universities, 2019, 40(3): 448.
Fig.3 FTIR spectra(A) of GO(a), Au@RGO(b), Fe3O4@RGO(c), Au@Fe3O4@RGO(d) and Au@Fe3O4@RGO-MIP(e) and ultraviolet(UV) spectra(B) of Au@RGO(a), Au@Fe3O4@RGO(b) and Au@Fe3O4@RGO-MIP(c)
Fig.4 CV curves of Au@RGO(a), Au@Fe3O4@RGO(b), Au@Fe3O4@RGO-MIP(c), Au@Fe3O4@RGO-MIP(d) after binding templateCV curves were recorded between -0.5 V to 0.5 V in 5 mmol/L K3[Fe(CN)6] solution containing 0.1 mol/L KCl at a scan rate of 50 mV/s.
Fig.5 Electrochemical impedance spectra of Au@RGO(a), Au@Fe3O4@RGO(b)(A), Au@Fe3O4@RGO-MIP(a) and Au@Fe3O4@RGO-MIP(b)(B) after binding templateEIS of various electrodes were recorded between -0.5 V to 0.5 V in 5 mmol/L K3[Fe(CN)6] solution containing 0.1 mol/L KCl at a scan rate of 50 mV/s.
Fig.6 CV curves of DBP detectionCV curves of various electrodes were recorded between -0.5 V to 0.5 V in 0.1 mol/L PBS solution at a scan rate of 50 mV/s.
Fig.7 Adsorption kinetic curve on the response to DBP for Au@Fe3O4@RGO-MIPs electrode in PBS solution containing 10 μmol/L DBPThe insert is the DBP for Au@Fe3O4@RGO-MIP at different times. DPV of various electrodes were recorded between -0.5 V to 0.5 V in 0.1 mol/L PBS solution at a scan rate of 50 mV/s, the amplitude of 50 mV, the pulse width of 50 ms, pulse cycle of 200 ms.
Fig.8 Different concentration curves of DBP on Au@Fe3O4@RGO-MIP and Au@Fe3O4@RGO-NIP(A) and linear relationship curve of Au@Fe3O4@RGO-MIP detects DBP(B)Inset is the DPV curves of Au@Fe3O4@RGO-MIP for different concentrations of DBP. DPV of various electrodes were recorded between -0.5 V to 0.5 V in 0.1 mol/L PBS solution at a scan rate of 50 mV/s, the amplitude of 50 mV, the pulse width of 50 ms, pulse cycle of 200 ms.
Sensor | LOD/(nmol·L-1) | Linear range/(μmol·L-1) | Ref. |
---|---|---|---|
MWCNTs@GONRs/GCE | 25.15 | 1.44—229.93 | [ |
DBP-MMIP-CL | 2.09 | 20.8—38400 | [ |
MGO@Au NPs-MIPs | 0.80 | 2.5—5 | [ |
Nano-Ni(OH)2 QCM | 17.96 | 0.018—0.072 | [ |
Au@Fe3O4@RGO-MIP | 0.305 | 0.01—0.1 | This work |
Table 1 Comparison with the other electrochemical sensors for determination of DBP
Sensor | LOD/(nmol·L-1) | Linear range/(μmol·L-1) | Ref. |
---|---|---|---|
MWCNTs@GONRs/GCE | 25.15 | 1.44—229.93 | [ |
DBP-MMIP-CL | 2.09 | 20.8—38400 | [ |
MGO@Au NPs-MIPs | 0.80 | 2.5—5 | [ |
Nano-Ni(OH)2 QCM | 17.96 | 0.018—0.072 | [ |
Au@Fe3O4@RGO-MIP | 0.305 | 0.01—0.1 | This work |
Fig.10 Response curve of Au@Fe3O4@RGO-MIP modified electrode to DBP concentration in lake water(A) and reproducibility of Au@Fe3O4@RGO-MIP for the detection of DBP(B)Inset of (A) is the calibration curve.
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