Synthesis, Characterization and Electrochemical Properties of a New Asymmetrical Nickel Phthalocyanine

Abstract

Abstract: A new asymmetrical nickel phthalocyanine(NiPc2 for short) was synthesized by increasing the temperature of the classical synthetic method, and its structure was characterized by MS, IR and UV-Vis-NIR spectroscopy. Meanwhile, a hypothetical mechanism was suggested and the electrochemical properties was studied by cyclic voltammetry. NiPc2 has strong absorption in near infrared region and prone to be J-aggregates because of the red-shift of the Q band. The NiPc2 has potential application on organic function devices.

Key words: Asymmetrical nickel phthalocyanine, NIR spectrum, Cyclic voltammetry, J-Aggregate

TrendMD:

GAO Jun-Shan, SHI Tie-Zheng, ZHAO Qing-Huan, DU Xi-Guang*, ZHANG Hai-Qian* . Synthesis, Characterization and Electrochemical Properties of a New Asymmetrical Nickel Phthalocyanine[J]. Chem. J. Chinese Universities, 2010, 31(8): 1585.

References

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