Synthesis and Crystal Structure of a New 3D Supramolecular Polyoxometalate (4,4’-bipy){[Ag(4,4’-bipy)]3[PMo12ⅥO40]}·H2O

Chem. J. Chinese Universities

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Synthesis and Crystal Structure of a New 3D Supramolecular Polyoxometalate (4,4’-bipy){[Ag(4,4’-bipy)]₃[PMo₁₂^ⅥO₄₀]}·H₂O

WANG Xiao-Lan^1,2, WANG En-Bo^1*, XU Xin-Xin¹, LI Yang-Guang¹

1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China;
2. Department of Chemistry, Baicheng Teacher’s College, Baicheng 137000, China

Received:2007-11-26 Revised:1900-01-01 Online:2008-10-10 Published:2008-10-10
Contact: WANG En-Bo

Abstract

Abstract: A new 3D supramolecular compound,(4,4’-bipy)[Ag(4,4’-bipy)]₃[PMo₁₂^ⅥO₄₀]·H₂O(1) was synthesized under mild hydrothermal condition, and the structure was characterized by elemental analysis, single crystal X-ray diffraction, IR and TGA. Compound 1 exhibits a photoluminescence property at room temperature. The structure of this compound consists of [PMo₁₂O₄₀]^3- anion, which is further connected by [Ag(4,4’-bipy)]₃⁺ unit to form a three-dimesional supramolecular network. Compound 1 crystallized in the triclinic system, space group P1, a=1.1275(2) nm, b=1.1910(2) nm, c=1.2898(3) nm, α=112.63(3)°, β=94.63(3)°, γ=99.53(3)°, V=1.5567(5) nm³, Z =1.

Key words: Polyoxometalate, Crystal structure, Supramolecule, Silver

CLC Number:

O614

TrendMD:

WANG Xiao-Lan^1,2, WANG En-Bo^1*, XU Xin-Xin¹, LI Yang-Guang¹. Synthesis and Crystal Structure of a New 3D Supramolecular Polyoxometalate (4,4’-bipy){[Ag(4,4’-bipy)]₃[PMo₁₂^ⅥO₄₀]}·H₂O[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Crystal Structure of a New 3D Supramolecular Polyoxometalate (4,4’-bipy){[Ag(4,4’-bipy)]₃[PMo₁₂^ⅥO₄₀]}·H₂O

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