Supramolecular Hydrogel Formed from Gelator with Low Molecular Weight Based on Hydrogen Bonds

Chem. J. Chinese Universities

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Supramolecular Hydrogel Formed from Gelator with Low Molecular Weight Based on Hydrogen Bonds

WANG Yu-Jiang, TANG Li-Ming, WANG Yan

Advanced Materials Laboratory, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2006-01-18 Revised:1900-01-01 Online:2006-08-10 Published:2006-08-10
Contact: TANG Li-Ming

Abstract

Abstract: A building unit(defined as SBU) synthesized from 1,2,4,5-benzene tetracarboxylic acid and 4-hydroxy pyridine was used as the gelator with low molecular weight to form supramolecular hydrogels at various concentrations. The dried hydrogels(xerogels) were observed by scanning electron microscope(SEM). The results indicate that the xerogels possess network structures composing of intertwined fibers and the dimension of the fibers can be regulated by the concentration of SBU. Powder X-ray diffraction(XRD) analysis indicates that the fibers are connected by SBU building units. The reversible sol-gel transition of the supramolecular system with the change of temperature was also noticed.

Key words: Supramolecular hydrogel, Gelator, Morphology

CLC Number:

O631

TrendMD:

WANG Yu-Jiang, TANG Li-Ming, WANG Yan. Supramolecular Hydrogel Formed from Gelator with Low Molecular Weight Based on Hydrogen Bonds[J]. Chem. J. Chinese Universities, doi: .

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Supramolecular Hydrogel Formed from Gelator with Low Molecular Weight Based on Hydrogen Bonds

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