Chem. J. Chinese Universities ›› 2017, Vol. 38 ›› Issue (6): 929.doi: 10.7503/cjcu20160845

• Special Articles of China International Conference on Electrospinning(CICE 2016) • Previous Articles     Next Articles

Electrospinning Preparation and Infrared-emissivity Properties of La0.67Ba0.33MnO3 Micro/nanofibers

LIU Jiawei, WANG Jianjiang*(), ZHAO Fang, XU Baocai   

  1. Advanced Material Institute, Ordnance Engineering College, Shijiazhuang 050003, China
  • Received:2016-11-24 Online:2017-06-10 Published:2017-02-22
  • Contact: WANG Jianjiang E-mail:JJWang63@heinfo.net
  • Supported by:
    This paper is supported by the Natural Science Foundation of Hebei Province, China(No.E2015506011).

Abstract:

Perovskite-type La0.67Ba0.33MnO3 micro/nanofibers were fabricated through electrospinning technology. The fibers were characterized by means of differential scanning calorimetry-thermogravimetric analysis(DSC-TGA), X-ray diffraction(XRD), Fourier transform infrared spectroscopy(FTIR) and scanning electron microscopy(SEM). The infrared emissivity of the fibers in the temperature range of 280—370 K was tested by IR-2 infrared-emissivity analyzer. The results show that perovskite structure is formed at 600 ℃. As the temperature increases, the morphology of samples changes from fiber to three-dimensional network structure, and eventually loses the fiber morphology. The infrared emissivity of La0.67Ba0.33MnO3 fibers calcined at 600 ℃ rises from 0.564 to 0.689 with the increase of temperature, which can be explained by the theory of double-exchange. The prospect of La0.67Ba0.33MnO3 fibers in variable infrared-emissivity materials is promising in the future.

Key words: La0.67Ba0.33MnO3, Micro/nanofibers, Morphology, Infrared-emissivity

CLC Number: 

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