A Special Layer Crystal Structure of Supera-molecule Fabricated by Aromatic Iodine-Cu(Ⅱ) Coordination Polymer

Abstract

Abstract: Copper(Ⅱ)-ferron(7-iodo-8-hydroxyquinoline-5-sulfonate) one-dimensional coordination polymer Na_2n[Cu(Ferron)₂]_n ·6 n H₂O was synthesized and investigated by X-ray diffraction method. The polymer exhibits a linear structure by the bis-iodine-axial coordination to the octahedral Cu(Ⅱ) center,which is stabilized by the iodine-aromatic ring(edge and face) and iodine-iodine interactions between the polymer lines,forming a special layer structure. The complex belongs to a triclinic system,space group P 1, a=0.648 4(19) nm, b=0.654 5(19) nm, c=1.911(6) nm, α=85.42(5)°,β=85.78(5)°,γ=72.99(4)°,V=0.772(4) nm³ and Z=1 .

Key words: 7-Iodo-8-hydroxyquinoline-5-sulfonate(Ferron), Metal complex, Weak interaction, Crystal structure

CLC Number:

O614

TrendMD:

ZHANG Feng, ZHANG Yang-Yang, GAO Xu, ZHANG Xiang-Dong, LI Yi-Zhi, CHEN Hui-Lan, LIU Qi-Tao . A Special Layer Crystal Structure of Supera-molecule Fabricated by Aromatic Iodine-Cu(Ⅱ) Coordination Polymer[J]. Chem. J. Chinese Universities, 2004, 25(8): 1422.

References

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