Synthesis and Physical Properties of Cobalt-Zinc Hybrid Porous Metal-organic Frameworks †

doi:10.7503/cjcu20190395

Abstract

Abstract:

Coordination polymer ZnCo(BTC)(OH)(H₂O)₃(NMP)(DMF)(H₂O)_1.5 was synthesized by slowly diffusing a balanced amount of organic amine into a solution of 1,3,5-benzenetricarboxylate(H₃BTC), zinc nitrate and cobalt nitrate. X-ray single crystal diffraction shows that the compound crystallizes in cubic, space group P2₁3, and its cell parameter is 1.43863(20) nm. Its physical properties were characterized by elemental analysis(EA), energy-dispersive X-ray spectroscopy(EDS), X-ray powder diffraction(XRD), N₂ sorption and variable-temperature magnetic susceptibility. The gas sorption shows this compound holds Ⅰ-isotherm characteristic of micropore, which is 0.84 nm of pore size and 832 m ²/g of langmiur surface area. The magnetic results show that it exhibits antiferromagnetism in the temperature range of 37—300 K.

Key words: Metal-organic frameworks, Coordination polymer, Heterometal complex, Magnetic property

CLC Number:

O611.4

TrendMD:

Baozhen SHI,Shan LI,Dianpeng WANG,Yunzhi ZHOU,Jinyu SUN. Synthesis and Physical Properties of Cobalt-Zinc Hybrid Porous Metal-organic Frameworks ^†[J]. Chem. J. Chinese Universities, 2019, 40(12): 2443.

Figures/Tables 7

References 31

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Empirical formula	C₉H₁₀O₁₀CoZn	θ range/(°)	2.00—28.62
Formula mass	402.47	Limiting indices	-18≤h≤17
Temperature/K	296(2)		-17≤k≤19
λ/nm	0.071073		-19≤l≤13
Crystal system	Cubic	Collected/unique reflns	20650/2467(R_int=0.0815)
Space group	P2₁3	Completeness to θ	97.5
a/nm	1.43863(20)	Refinement method on F²	Full-matrix least-squares
V/nm³	2.9775(7)	Data/restraints/parameters	2467/1/69
Z	4	Goodness-of-fit on F²	0.924
D_calcd./(Mg·m^-3)	0.898	Final R indices[I>2σ(I)]	R₁=0.0705, wR₂=0.1802
μ/mm^-1	1.384	R indices(all data)	R₁=0.1192, wR₂=0.1998
F(000)	804	Δρ_max, Δρ_min/(e·nm^-3)	538, -314

Empirical formula	C₉H₁₀O₁₀CoZn	θ range/(°)	2.00—28.62
Formula mass	402.47	Limiting indices	-18≤h≤17
Temperature/K	296(2)		-17≤k≤19
λ/nm	0.071073		-19≤l≤13
Crystal system	Cubic	Collected/unique reflns	20650/2467(R_int=0.0815)
Space group	P2₁3	Completeness to θ	97.5
a/nm	1.43863(20)	Refinement method on F²	Full-matrix least-squares
V/nm³	2.9775(7)	Data/restraints/parameters	2467/1/69
Z	4	Goodness-of-fit on F²	0.924
D_calcd./(Mg·m^-3)	0.898	Final R indices[I>2σ(I)]	R₁=0.0705, wR₂=0.1802
μ/mm^-1	1.384	R indices(all data)	R₁=0.1192, wR₂=0.1998
F(000)	804	Δρ_max, Δρ_min/(e·nm^-3)	538, -314