Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (2): 345.

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Hydrothermal Preparation of Highly-oriented ZnO Nanorod Array Films

GUO Min1, DIAO Peng2, CAI Sheng-Min1   

  1. 1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
    2. School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100083, China
  • Received:2003-08-26 Online:2004-02-24 Published:2004-02-24

Abstract: By using a simply and low-temperature hydrothermal method, ZnO nanorod array films with narrow size distribution and high orientation consistence were successfully prepared on ITO substrates, which were pre-treated with ZnO colloid solution. The obtained ZnO nanostructure was characterized by XRD and SEM. The results of characterization indicate that the nanorods are high-quality single crystals growing along (001) direction with a high consistent orientation perpendicular to the substrate. SEM images show that the nanorods have a very narrow size distribution of 20—50 nm with the average diameter about 40 nm. The room temperature photoluminescence of the as-prepared ZnO films exhibits a strong UV emission at about 390 nm and a weak emission at about 460 nm. The ease of fabricating high-quality ZnO nanorod arrays in large scales will greatly promote the fundamental research and practical applications of the ordered one-dimention ZnO structure in various fields of nanoscale science and technology.

Key words: ZnO, Nanorod array films, Hydrothermal method

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