Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (12): 2381.

• Articles • Previous Articles     Next Articles

Synthesis of a Novel Macromolecular Coupling Agent from ATRP

ZHANG Hong-Wen1, AI Peng1, JIANG Yan1,2, LI Hong-Tu1, ZHANG Kai1, YANG Song-Ru1, WANG Jing-Yuan1   

  1. 1. College of Chemistry, Jilin University, Changchun 130023, China;
    2. College of Life Science, Qiqihaer University, Qiqihaer 161006, China
  • Received:2003-12-30 Online:2004-12-24 Published:2004-12-24

Abstract: A novel graft macromolecular coupling agent with well-defined structure was synthesized by atom transfer radical polymerization(ATRP). Since the silicon of graft polymers possesses a strong affinity to hydroxyl mineral, it gives fillers some new properties such as the increase of the interaction of fillers with matrix. The properties, structure of macromolecular coupling agent and its composite were studied by dynamic mechanical spectra, IR, UV, NMR, GPC and SEM.

Key words: Atom transfer radical polymerization(ATRP), Macromolecular coupling agent, Damping, Compatibility

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