Chem. J. Chinese Universities ›› 2019, Vol. 40 ›› Issue (7): 1571.doi: 10.7503/cjcu20190016
• Polymer Chemistry • Previous Articles
ZHANG Xinping, ZHANG Jianping, CAI Lei, ZONG Xin, HE Aihua*()
Received:
2019-01-07
Online:
2019-07-10
Published:
2019-07-12
Contact:
HE Aihua
E-mail:aihuahe@iccas.ac.cn
Supported by:
CLC Number:
TrendMD:
ZHANG Xinping, ZHANG Jianping, CAI Lei, ZONG Xin, HE Aihua. Structure and Properties of Damping Materials with Super Fatigue Resistance Based on Chloroprene Rubber†[J]. Chem. J. Chinese Universities, 2019, 40(7): 1571.
System m(CR):m(TBIR) | Unfilled gum | Filled compound | |||||||
---|---|---|---|---|---|---|---|---|---|
100:0 | 90:10 | 80:20 | 70:30 | 100:0 | 90:10 | 80:20 | 70:30 | ||
ML/(dN·m) | 0.85 | 0.96 | 1.06 | 1.26 | 2.97 | 2.96 | 3.13 | 3.59 | |
MH/(dN·m) | 11.41 | 9.50 | 8.38 | 7.76 | 28.55 | 23.62 | 21.54 | 20.85 | |
MH-ML/(dN·m) | 10.56 | 8.54 | 7.32 | 6.50 | 25.58 | 20.66 | 18.41 | 17.26 | |
t10/min | 1.87 | 1.76 | 1.79 | 1.71 | 1.48 | 1.36 | 1.31 | 1.32 | |
t90/min | 19.93 | 18.66 | 17.65 | 17.47 | 19.00 | 16.74 | 15.58 | 14.15 | |
vr/min-1 | 5.54 | 5.92 | 6.30 | 6.34 | 5.71 | 6.50 | 7.01 | 7.79 |
Table 1 Curing characteristics of unfilled CR/TBIR gums and filled CR/TBIR compounds
System m(CR):m(TBIR) | Unfilled gum | Filled compound | |||||||
---|---|---|---|---|---|---|---|---|---|
100:0 | 90:10 | 80:20 | 70:30 | 100:0 | 90:10 | 80:20 | 70:30 | ||
ML/(dN·m) | 0.85 | 0.96 | 1.06 | 1.26 | 2.97 | 2.96 | 3.13 | 3.59 | |
MH/(dN·m) | 11.41 | 9.50 | 8.38 | 7.76 | 28.55 | 23.62 | 21.54 | 20.85 | |
MH-ML/(dN·m) | 10.56 | 8.54 | 7.32 | 6.50 | 25.58 | 20.66 | 18.41 | 17.26 | |
t10/min | 1.87 | 1.76 | 1.79 | 1.71 | 1.48 | 1.36 | 1.31 | 1.32 | |
t90/min | 19.93 | 18.66 | 17.65 | 17.47 | 19.00 | 16.74 | 15.58 | 14.15 | |
vr/min-1 | 5.54 | 5.92 | 6.30 | 6.34 | 5.71 | 6.50 | 7.01 | 7.79 |
m(CR):m(TBIR) | Aggregate size/μm | Dispersion degree(%) |
---|---|---|
100:0 | 12.70 | 75.36 |
90:10 | 12.60 | 77.37 |
80:20 | 12.44 | 77.61 |
70:30 | 12.43 | 77.46 |
Table 2 Filler dispersion and mean aggregate size in filled CR/TBIR vulcanizates
m(CR):m(TBIR) | Aggregate size/μm | Dispersion degree(%) |
---|---|---|
100:0 | 12.70 | 75.36 |
90:10 | 12.60 | 77.37 |
80:20 | 12.44 | 77.61 |
70:30 | 12.43 | 77.46 |
System m(CR):m(TBIR) | Unfilled CR/TBIR vulcanizates | Filled CR/TBIR vulcanizates | ||||||
---|---|---|---|---|---|---|---|---|
100:0 | 90:10 | 80:20 | 70:30 | 100:0 | 90:10 | 80:20 | 70:30 | |
Tensile strength/MPa | 10.5 | 12.9 | 13.0 | 13.8 | 19.6 | 19.8 | 20.2 | 20.4 |
Modulus at 100%/MPa | 1.09 | 1.07 | 1.08 | 1.06 | 4.45 | 4.04 | 4.02 | 3.62 |
Modulus at 300%/MPa | 1.68 | 1.64 | 1.65 | 1.67 | — | — | 20.02 | 16.71 |
Elongation at break(%) | 675 | 711 | 726 | 782 | 277 | 283 | 310 | 353 |
Tear strength/(kN·m-1) | 46.6 | 50.8 | 52.2 | 51.8 | 114.3 | 111.0 | 117.3 | 115.6 |
Shore A hardness/(°) | 53 | 53 | 57 | 59 | 73 | 74 | 76 | 77 |
Rebound(%) | 59 | 57 | 56 | 54 | 44 | 41 | 38 | 37 |
Compression set(%) | 15.2 | 14.4 | 14.3 | 13.5 | 17.6 | 17.2 | 16.4 | 16.0 |
Heat built-up/℃ | — | — | 24.1 | 21.7 | 43.8 | 41.8 | 40.2 | 38.7 |
Aging under air at 100 ℃ for 72 h | ||||||||
Tensile strength/MPa | 5.4 | 6.0 | 6.5 | 7.3 | 19.2 | 17.8 | 16.8 | 15.4 |
Modulus at 100%/MPa | 1.31 | 1.12 | 0.98 | 0.92 | 6.26 | 4.98 | 4.32 | 4.03 |
Modulus at 300%/MPa | 2.31 | 1.95 | 1.76 | 1.73 | — | — | — | — |
Elongation at break(%) | 534 | 554 | 580 | 610 | 212 | 239 | 262 | 270 |
Aging coefficient(%) | 40.7 | 36.2 | 39.9 | 40.2 | 75.0 | 73.2 | 70.2 | 56.2 |
Table 3 Mechanical properties of unfilled and filled CR/TBIR vulcanizates
System m(CR):m(TBIR) | Unfilled CR/TBIR vulcanizates | Filled CR/TBIR vulcanizates | ||||||
---|---|---|---|---|---|---|---|---|
100:0 | 90:10 | 80:20 | 70:30 | 100:0 | 90:10 | 80:20 | 70:30 | |
Tensile strength/MPa | 10.5 | 12.9 | 13.0 | 13.8 | 19.6 | 19.8 | 20.2 | 20.4 |
Modulus at 100%/MPa | 1.09 | 1.07 | 1.08 | 1.06 | 4.45 | 4.04 | 4.02 | 3.62 |
Modulus at 300%/MPa | 1.68 | 1.64 | 1.65 | 1.67 | — | — | 20.02 | 16.71 |
Elongation at break(%) | 675 | 711 | 726 | 782 | 277 | 283 | 310 | 353 |
Tear strength/(kN·m-1) | 46.6 | 50.8 | 52.2 | 51.8 | 114.3 | 111.0 | 117.3 | 115.6 |
Shore A hardness/(°) | 53 | 53 | 57 | 59 | 73 | 74 | 76 | 77 |
Rebound(%) | 59 | 57 | 56 | 54 | 44 | 41 | 38 | 37 |
Compression set(%) | 15.2 | 14.4 | 14.3 | 13.5 | 17.6 | 17.2 | 16.4 | 16.0 |
Heat built-up/℃ | — | — | 24.1 | 21.7 | 43.8 | 41.8 | 40.2 | 38.7 |
Aging under air at 100 ℃ for 72 h | ||||||||
Tensile strength/MPa | 5.4 | 6.0 | 6.5 | 7.3 | 19.2 | 17.8 | 16.8 | 15.4 |
Modulus at 100%/MPa | 1.31 | 1.12 | 0.98 | 0.92 | 6.26 | 4.98 | 4.32 | 4.03 |
Modulus at 300%/MPa | 2.31 | 1.95 | 1.76 | 1.73 | — | — | — | — |
Elongation at break(%) | 534 | 554 | 580 | 610 | 212 | 239 | 262 | 270 |
Aging coefficient(%) | 40.7 | 36.2 | 39.9 | 40.2 | 75.0 | 73.2 | 70.2 | 56.2 |
Fig.5 Flexual fatigue resistance performances of unfilled(A, B) and filled CR/TBIR vulcanizates(C, D)(A, C) The 1st flexural fatigue cycles; (B, D) the 6th flexural fatigue cycles.
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