Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (8): 1397.

• Articles • Previous Articles     Next Articles

A Kind of CdSNanocluster with Free Carboxyl Groups on Its Surface

JIANG Lin, CHEN Xia, YANG Wen-Sheng, JIN Jian-YANG Bai-Quan, XU Li, LI Tie-Jin   

  1. Center for Intelligent Materials United Research, Department of Chemistry, Jilin University, Changchun 130023, China
  • Received:2000-01-13 Online:2001-08-24 Published:2001-08-24

Abstract: CdSnanoclusters were directly synthesizeDIn aqueous solution by using mercaptoacetic acid as the stabilizer. The results of TEM(Transmission Electron Microscopy) and ED(Electron Diffraction) show that the structures and aggregations of the resulting CdSnanoclusters can be affected by the molar ratio of mercaptoacetic acid and Cd 2+ ion. When the ratio was high, the resulting nanoclusters were observed as densely packed layer structure on the template. When the ratio was low, the prepared CdSnanoclusters can not form highly aggregated structure. Fluorescence spectra of the CdSnanoclusters show a strong yellow fluorescence.

Key words: CdS, Nanocluster, Mercaptoacetic aicd, Fluorescence spectroscopy

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