Synthesis and Characteristics of Compounds Having Both Photochromic and Fluorescent Character

Abstract

Abstract: Eight new compounds which have both photochromic and fluorescent character have been synthesized by esterification reaction in the presence of DCC from the derivatives of indolinospirobenzopyrans and coumarins. The structure of these new compounds were identified and their spectrum properties were studied. The new compounds were shown to be have both photochromism character and fluorecent character, and their fluorescent spectrum have two exciting wavelength and two different emitting peak respectively. They were expected to be applied in such areas as anti forgery materials, bio-labeling reagents, and other multiple functional materials.

Key words: Indolinospirobenzopyran, Coumarin, UV reflection spectra, Fluorescence spectrum

CLC Number:

O626

TrendMD:

PANG Mei-Li, WANG Yong-Mei, MENG Ji-Ben, WANG Ji-Tao . Synthesis and Characteristics of Compounds Having Both Photochromic and Fluorescent Character[J]. Chem. J. Chinese Universities, 2000, 21(6): 903.

[1]	TANG Qian, DAN Feijun, GUO Tao, LAN Haichuang. Synthesis and Application of Quinolinone-coumarin-based Colorimetric Fluorescent Probe for Recognition of Hg²⁺ [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210660.
[2]	LI Lun, ZHANG Jingyan, LUO Jing, LIU Ren, ZHU Yi. Synthesis and Properties of UV/Vis-LED Excitable Photoinitiators Based on Coumarin Pyridinium Salt [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220178.
[3]	ZHAO Huijun, WU Tong, SUN Yue, DUAN Lian, MA Yanyu. A Coumarin-based Ratiometric Fluorescent Probe for BF₃ Detection in Solution and Air [J]. Chem. J. Chinese Universities, 2021, 42(8): 2422.
[4]	KUANG Xiaojun, YI Jingwei, FANG Xiaoxia, LAI Dongmei, XU Hong. Preparation of Water-soluble Coumarin Fluorescent Substrate and Its Application in Droplet Based Digital Detection [J]. Chem. J. Chinese Universities, 2021, 42(11): 3537.
[5]	MA Xiangying, LIAO Yanjun, QIN Fanghong, YIN Yuanhao, HUANG Zaiyin, CHEN Qifeng. Study on the Photocatalytic Performance of Carbon Doped g-C₃N₄ Based on in situ Photomicrocalorimeter-fluorescence Spectrometry [J]. Chem. J. Chinese Universities, 2020, 41(11): 2526.
[6]	MA Yukun, WANG Haijun, GUO Mengyan. Preparation of ECB Molecularly Imprinted Film Fluorescent Sensor for Detection of Traditional Chinese Herbal Medicine^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1381.
[7]	HAN Tao,CAI Xiaoxia,LI Cong,QIAO Congde,ZHAO Hui. Preparation and Properties Characterization of Biobased Dihydrocoumarin Toughened Epoxy Resin^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 1043.
[8]	BAI Lei,HUO Shuhui,CHEN Jing,LU Xiaoquan. Squaramide Fluorescence Probe for Chiral Recognition of α-Amino Acids^† [J]. Chem. J. Chinese Universities, 2019, 40(1): 41.
[9]	HAN Ruixia,LÜ Jitao,ZHANG Shuzhen. Molecular Probe for the Determination of Hydroxyl Radicals in Heterogeneous Systems: Coumarin^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2658.
[10]	LI Yang, LI Zhiwen, ZHU Junfei, LIU Shihui, HE Junlin. Construction of Pyrenyl Pairs in dsDNA: Fluorescent Properties of Multiple Pyrenyl-attached dsDNAs Through 7-Substituted 8-Aza-7-deaza-2'-deoxyadenosine Analogues^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2206.
[11]	WAN Ting, LI Xingxing, HUANG Zaiyin, QIU Jiangyuan, ZUO Chen, TAN Xuecai. In-situ Photocatalytic Process of Rhodamine B over g-C₃N₄@Ag₃PO₄ Nanocomposites Based on Photomicrocalorimeter-fluorescence Spectrometry^† [J]. Chem. J. Chinese Universities, 2017, 38(12): 2226.
[12]	QIAN Liwei, LI Ji, SONG Wenqi, HU Xiaoling, GUAN Ping. Utilizing Macromolecular Chain as Functional Monomer and Crosslinker to Imprint BSA with Preserving the Structural Integrity of Template^† [J]. Chem. J. Chinese Universities, 2016, 37(11): 2092.
[13]	ZHANG Jing, JIANG Yuliang, CHENG Yu, GU Weijin, WANG Bingxiang. Microwave Synthesis of Glycerol Carbon Quantum Dots and Its Application in Fe³⁺ Probe^† [J]. Chem. J. Chinese Universities, 2016, 37(1): 54.
[14]	XIANG Junfeng, YI Pinggui, YU Xianyong, CHEN Jian, HAO Yanlei, REN Zhiyong. Excited-state Proton Transfer of 2-(2-Hydroxyphenyl)benzothiazole in the Confined Nanocavity^† [J]. Chem. J. Chinese Universities, 2015, 36(4): 654.
[15]	DONG Lu, YI Zhongsheng, WU Zhiwei, WANG Haiyang, ZHANG Aiqian. Mechanism Study on the Interaction Between 2'-Hydroxy-2,4-dibromo Diphenyl Ethers and Human Serum Albumin Based on Spectroscopic Methods and Computional Simulations^† [J]. Chem. J. Chinese Universities, 2015, 36(3): 516.

Synthesis and Characteristics of Compounds Having Both Photochromic and Fluorescent Character

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments